Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics

被引：101

作者：

Cordier, S. ^{[1
]}

Grasset, F. ^{[1
,2
]}

Molard, Y. ^{[1
]}

Amela-Cortes, M. ^{[1
]}

Boukherroub, R. ^{[3
]}

Ravaine, S. ^{[4
]}

Mortier, M. ^{[5
]}

Ohashi, N. ^{[6
]}

Saito, N. ^{[6
]}

Haneda, H. ^{[6
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes, Campus Beaulieu, F-35042 Rennes, France

[2] Natl Inst Mat Sci, CNRS, UMI 3629, Lab Innovat Key Mat & Struct LINK, Tsukuba, Ibaraki 3050044, Japan

[3] Univ Lille 1, IRI, USR CNRS 3078, F-59658 Villeneuve Dascq, France

[4] Univ Bordeaux, CNRS, CRPP, UPR 8641, F-33600 Pessac, France

[5] CNRS, Chim ParisTech, Inst Rech Chim Paris, F-75005 Paris, France

[6] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2015年 / 25卷 / 02期

关键词：

Nanoarchitectonics; Metal nanoclusters; Molybdenum; Near infra-red; Hybrids; Liquid crystal; Microemulsion; IN-OIL MICROEMULSION; METAL ATOM CLUSTERS; ONE-POT SYNTHESIS; HEXANUCLEAR MOLYBDENUM; LUMINESCENT MATERIALS; SILICA NANOPARTICLES; HALIDE CLUSTERS; MO-4; CLUSTERS; PLANAR DEFECT; CRYSTAL;

D O I：

10.1007/s10904-014-0112-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recently, Nanoarchitectonics has been introduced as a new concept that refers to a technology system for arranging nanoscale structural units in a required architecture. Multifunctional properties are achieved by a combination of several materials in a well-defined architecture. In the frame of this concept, composite nanoarchitectures represent a new class of nanostructured entities that integrate various dissimilar nanoscale building blocks including clusters, particles, wires and films. The heterogeneous composite nanostructured materials are composed by definition of multi-(nano)components, each tailored to address different requirements. As one of the nanocomponents, nanometer sized metal clusters (< 2 nm), which consist of less than a few dozens of metal atoms, could be defined as a link between atom and nanoparticle. In this paper, we will focus on our results on new nano-composites involving Mo-6 atom nanosized cluster units for optical, nanobiotechnology, energy and environmental applications.

引用

页码：189 / 204

页数：16

共 125 条

[1] Luminescence of salts and copolymers containing the (MoII6Cl8)4+ cluster [J].