A facile enantioselective synthesis of 2-(2-aminoethyl)allylsilanes, new synthons for piperidine synthesis

被引：14
|
作者：
Monfray, J [1 ]
Gelas-Mialhe, Y [1 ]
Gramain, JC [1 ]
Remuson, R [1 ]
机构：
[1] Univ Clermont Ferrand, CNRS, UMR 6504, Lab SEESIB, F-63177 Clermont Ferrand, France
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 31期
关键词：
allylsilane; organocerium; amine; diastereoselectivity;
D O I：
10.1016/S0040-4039(03)01428-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of chiral (2-substituted-2-aminoethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition to the ester group of non racemic chiral beta-aminoesters is described. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5785 / 5787
页数：3
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