A facile enantioselective synthesis of 2-(2-aminoethyl)allylsilanes, new synthons for piperidine synthesis

被引：14

作者：

Monfray, J ^{[1
]}

Gelas-Mialhe, Y ^{[1
]}

Gramain, JC ^{[1
]}

Remuson, R ^{[1
]}

机构：

[1] Univ Clermont Ferrand, CNRS, UMR 6504, Lab SEESIB, F-63177 Clermont Ferrand, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 31期

关键词：

allylsilane; organocerium; amine; diastereoselectivity;

D O I：

10.1016/S0040-4039(03)01428-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of chiral (2-substituted-2-aminoethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition to the ester group of non racemic chiral beta-aminoesters is described. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：5785 / 5787

页数：3

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