Polyethylenimine modified magnetic graphene oxide nanocomposites for Cu2+ removal

被引:58
|
作者
Sui, Ning [1 ]
Wang, Lina [3 ]
Wu, Xiaohan [1 ]
Li, Xinghua [1 ]
Sui, Jing [1 ]
Xiao, Hailian [1 ]
Liu, Manhong [1 ]
Wan, Jun [3 ]
Yu, William W. [1 ,2 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266042, Peoples R China
[2] Louisiana State Univ, Dept Chem & Phys, Shreveport, LA 71115 USA
[3] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China
关键词
HEAVY-METAL IONS; FE3O4; NANOPARTICLES; AQUEOUS-SOLUTION; EQUILIBRIUM; ADSORPTION; ADSORBENT; CU(II); COMPOSITE; CHITOSAN; COPPER;
D O I
10.1039/c4ra11669k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fe3O4 nanoparticles were synthesized on graphene oxide (GO), then mixed with polyethylenimine to obtain GO/Fe3O4/PEI nanocomposites. Due to the high surface area of GO, superparamagnetism of Fe3O4, and excellent complex ability of PEI, the nanocomposites showed extremely high Cu2+ removal efficiency. The Cu2+ removal capacity was 157 mg g(-1), which is higher than most reported results. The adsorption kinetics could be best described by a pseudo-second-order model. Moreover, GO/Fe3O4/PEI nanocomposites could be easily recycled by magnetic separation. After five cycles, the removal efficiency remained 84%.
引用
收藏
页码:746 / 752
页数:7
相关论文
共 50 条
  • [1] A strong adsorbent for Cu2+: graphene oxide modified with triethanolamine
    Liu, Gonggang
    Gui, Shan
    Zhou, Hao
    Zeng, Fantao
    Zhou, Yonghua
    Ye, Hongqi
    DALTON TRANSACTIONS, 2014, 43 (19) : 6977 - 6980
  • [2] Folding/aggregation of graphene oxide and its application in Cu2+ removal
    Yang, Sheng-Tao
    Chang, Yanli
    Wang, Haifang
    Liu, Gangbo
    Chen, Sheng
    Wang, Yanwen
    Liu, Yuanfang
    Cao, Aoneng
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 351 (01) : 122 - 127
  • [3] Preparation and characterization of magnetic chitosan nanocomposites for removal of Cu2+ from aqueous solution
    Zhang, Chuandong
    Ma, Jiangquan
    Zhao, Yun
    Li, Zhengping
    Liu, Wenjie
    Yao, Chao
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2018, 39 (04) : 491 - 496
  • [4] Effective removal of copper from aqueous solutions by modified magnetic chitosan/graphene oxide nanocomposites
    Hosseinzadeh, Hossein
    Ramin, Sonia
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 113 : 859 - 868
  • [5] Reduced graphene oxide enhanced magnetic nanocomposites for removal of carbamazepine
    Jiang, Yijie
    Chen, Dezhi
    Yang, Wu
    Wu, Shaolin
    Luo, Xubiao
    JOURNAL OF MATERIALS SCIENCE, 2018, 53 (22) : 15474 - 15486
  • [6] Reduced graphene oxide enhanced magnetic nanocomposites for removal of carbamazepine
    Yijie Jiang
    Dezhi Chen
    Wu Yang
    Shaolin Wu
    Xubiao Luo
    Journal of Materials Science, 2018, 53 : 15474 - 15486
  • [7] A Simple Green Synthesis Route for the Reduction of Graphene Oxide and Its Application to Cu2+ Removal
    Singh, Vivek K.
    Han, Seung H.
    Yeon, Ju-Rang
    Kim, Ji-Hyun
    Shin, Koo
    SCIENCE OF ADVANCED MATERIALS, 2013, 5 (06) : 566 - 574
  • [8] The preparation of modified boehmite/PMMA nanocomposites by in situ polymerization and the assessment of their capability for Cu2+ ion removal
    Mohammadnezhad, Gholamhossein
    Dinari, Mohammad
    Soltani, Roozbeh
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (04) : 3612 - 3621
  • [9] 3-Carboxybenzoboroxole Functionalized Polyethylenimine Modified Magnetic Graphene Oxide Nanocomposites for Human Plasma Glycoproteins Enrichment under Physiological Conditions
    Wu, Qiong
    Jiang, Bo
    Weng, Yejing
    Liu, Jianxi
    Li, Senwu
    Hu, Yechen
    Yang, Kaiguang
    Liang, Zhen
    Zhang, Lihua
    Zhang, Yukui
    ANALYTICAL CHEMISTRY, 2018, 90 (04) : 2671 - 2677
  • [10] Graphene Oxide-Based Electrodes with Constant Magnetic Field-Assisted Electrodeposition System to Raising the Efficient of Cu2+ Removal
    Zaid, Khayri
    Zorah, Mohammed
    Ameer, Ali
    Yuet, Fanny Kho Chee
    REVUE DES COMPOSITES ET DES MATERIAUX AVANCES-JOURNAL OF COMPOSITE AND ADVANCED MATERIALS, 2024, 34 (05): : 581 - 591