Mechanism of the reaction of xenon tetraoxide with hydrogen: A photochemical reaction

被引：0
|
作者：
Aleinikov, NN [1 ]
Vasil'ev, GK [1 ]
Kashtanov, SA [1 ]
Makarov, EF [1 ]
Chernyshev, YA [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源：
KINETICS AND CATALYSIS | 2001年 / 42卷 / 02期
关键词：
D O I：
10.1023/A:1010469418851
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dependence of the rate of a photochemical reaction of XeO4 with H-2 On the concentrations of H2 and the diluent gases He and CO2 is studied at room temperature. The results are compared with the data for the dark reaction. A mechanism with the elementary energetic branched-chain reaction OH(v) + XeO4 --> OH + O + XeO3 is proposed to explain the results of the study.
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页码：233 / 237
页数：5
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