Oriented Salts: Dimension-Controlled Charge-by-Charge Assemblies from Planar Receptor-Anion Complexes

被引:128
作者
Haketa, Yohei [1 ]
Sasaki, Sono [2 ,3 ]
Ohta, Noboru [2 ]
Masunaga, Hiroyasu [2 ]
Ogawa, Hiroki [2 ]
Mizuno, Nobuhiro [2 ]
Araoka, Fumito [4 ]
Takezoe, Hideo [4 ]
Maeda, Hiromitsu [1 ,5 ]
机构
[1] Ritsumeikan Univ, Inst Sci & Engn, Coll Pharmaceut Sci, Kusatsu 5258577, Japan
[2] Japan Synchrotron Radiat Res Inst JASRI, Sayo 6795198, Japan
[3] Kyoto Inst Technol, Grad Sch Sci & Technol, Dept Biobased Mat Sci, Kyoto 6068585, Japan
[4] Tokyo Inst Technol, Inst Sci & Engn, Dept Organ & Polymer Mat, Tokyo 1528522, Japan
[5] PRESTO Japan Sci & Technol Agcy JST, Kawaguchi, Saitama 3320012, Japan
关键词
gels; host-guest systems; ion pairs; nanostructures; supramolecular chemistry; TEMPERATURE IONIC LIQUIDS; SELF-ORGANIZATION; METAL;
D O I
10.1002/anie.201006356
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pillars of salts: By combining planar cations and planar anionic structures based on π-conjugated acyclic dipyrroles containing an anion, charge-by-charge assemblies could be formed (see picture). Not only crystals but also soft materials, such as supramolecular gels and thermotropic liquid crystals, could be made by this method. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:10079 / 10083
页数:5
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