Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal

被引：57

作者：

Hijikata, Yuh ^{[1
]}

Horike, Satoshi ^{[1
]}

Tanaka, Daisuke ^{[1
,2
,3
]}

Groll, Juergen ^{[2
,3
]}

Mizuno, Motohiro ^{[4
]}

Kim, Jungeun ^{[5
]}

Takata, Masaki ^{[5
,6
]}

Kitagawa, Susumu ^{[1
,7
,8
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Rhein Westfal TH Aachen, DWI eV, D-52056 Aachen, Germany

[3] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52056 Aachen, Germany

[4] Kanazawa Univ, Grad Sch Nat Sci & Technol, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

[5] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

[6] RIKEN, SPring Ctr 8, Sayo, Hyogo 6795148, Japan

[7] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[8] Japan Sci & Technol Agcy JST, ERATO, Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期

关键词：

METAL-ORGANIC FRAMEWORK; COORDINATION-POLYMER; LATTICE CONTRACTION; M-II; NANOPARTICLES; TEMPERATURE; SORPTION; SIZE; NANOSTRUCTURES; TRANSFORMATION;

D O I：

10.1039/c1cc10983a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have demonstrated downsizing effects of the soft porous crystal, [Zn(isophthalate)(4,40-bipyridyl)](n) (CID-1), on the adsorption behavior between CID-1 and CID-1 nanocrystal (NCID-1). The difference results from the packing crystal structures and the dynamics of the frameworks.

引用

页码：7632 / 7634

页数：3

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