alpha-carbonyl radicals for total synthesis of natural products

被引：5

作者：

Sha, CK

Jean, TS

Yau, NT

Huang, SJ

Chiou, RT

Young, JF

Lih, SH

Tseng, WH

机构：

[1] Department of Chemistry, National Tsing Hua University

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030687

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha-Carbonyl radicals, generated from the corresponding alpha-iodo ketones, enones, or vinylogous esters and amides, undergo intramolecular cyclization to the tethered trimethylsilylacetylenic side chain to afford the bicyclic vinylsilane ketone or enones. These radical cyclizations are applied to total syntheses of natural products.

引用

页码：687 / 689

页数：3

共 6 条

[1] NATURALLY-OCCURRING TERPENE DERIVATIVES .286. TRICYCLIC SESQUITERPENES AND FURTHER DITERPENES FROM ESPELETIOPSIS SPECIES [J].