A fluoride ion-mediated continuous etching-redeposition strategy to synthesize Si nanocomposites with appropriate SiO2 coating layers for Li-ion batteries

被引:15
作者
Fan, Xiaoming [1 ,2 ]
Zhao, Junhao [1 ]
Yang, Zeheng [1 ]
Zhang, Weixin [1 ]
机构
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Anhui, Peoples R China
[2] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
关键词
SILICON NANOWIRES; ANODE MATERIALS; DESIGN;
D O I
10.1039/c8cc05034a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silicon nanocomposites with surface coating have been promising candidates for high-performance anodes in Li-ion batteries. Here we report a simple yet effective way to synthesize Si@SiO2 nanocomposites with amorphous SiO2 coating through a fluoride ion-mediated continuous etching-redeposition process. The Si@SiO2 nanocomposite anode exhibits significantly improved lithium storage properties, with a reversible capacity of 1356 mA h g(-1) at 2.1 A g(-1) for 300 cycles.
引用
收藏
页码:12447 / 12450
页数:5
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