Poly(3,4-ethylenedioxythiophene) (PEDOT) Derivatives: Innovative Conductive Polymers for Bioelectronics

被引：208

作者：

Mantione, Daniele ^{[1
]}

del Agua, Isabel ^{[1
,2
]}

Sanchez-Sanchez, Ana ^{[1
,2
]}

Mecerreyes, David ^{[1
,3
]}

机构：

[1] Polymat Univ Basque Country UPV EHU, Joxe Mari Korta Ctr, Avda Tolosa 72, Donostia San Sebastian 20018, Spain

[2] MOC, CMP EMSE, Ecole Natl Super Mines, Dept Bioelect, F-13541 Gardanne, France

[3] Ikerbasque, Basque Fdn Sci, E-48011 Bilbao, Spain

来源：

POLYMERS | 2017年 / 9卷 / 08期

关键词：

PEDOT; conducting polymers; biopolymers; bioelectronics; ELECTROCHEMICAL SYNTHESIS; ELECTRICAL-CONDUCTIVITY; POST-FUNCTIONALIZATION; ELECTROCHROMIC DEVICE; AQUEOUS DISPERSIONS; CONJUGATED POLYMERS; HUISGEN REACTION; HIGH ADHESION; THIN-FILMS; SURFACES;

D O I：

10.3390/polym9080354

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(3,4-ethylenedioxythiophene)s are the conducting polymers (CP) with the biggest prospects in the field of bioelectronics due to their combination of characteristics (conductivity, stability, transparency and biocompatibility). The gold standard material is the commercially available poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT:PSS). However, in order to well connect the two fields of biology and electronics, PEDOT: PSS presents some limitations associated with its low (bio) functionality. In this review, we provide an insight into the synthesis and applications of innovative poly(ethylenedioxythiophene)-type materials for bioelectronics. First, we present a detailed analysis of the different synthetic routes to (bio) functional dioxythiophene monomer/polymer derivatives. Second, we focus on the preparation of PEDOT dispersions using different biopolymers and biomolecules as dopants and stabilizers. To finish, we review the applications of innovative PEDOT-type materials such as biocompatible conducting polymer layers, conducting hydrogels, biosensors, selective detachment of cells, scaffolds for tissue engineering, electrodes for electrophysiology, implantable electrodes, stimulation of neuronal cells or pan-bio electronics.

引用

页数：21

共 131 条

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