Metal-Organic Framework Regioisomers Based on Bifunctional Ligands

被引：55

作者：

Kim, Min ^{[1
]}

Boissonnault, Jake A. ^{[1
]}

Phuong V. Dau ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

基金：

美国国家科学基金会;

关键词：

bifunctional MOFs; framework flexibility; metal-organic frameworks; porous solids; regioisomers; N-BROMOSUCCINIMIDE;

D O I：

10.1002/anie.201106429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regioisomeric MOFs: A series of bifunctional metal-organic framework (MOF) regioisomers has been produced from amino-halo benzene dicarboxylate (NH 2X-BDC) ligands. Zr IV- and Zn II-based MOFs were synthesized and for the flexbile Zn II-based MOFs, gas sorption properties were dependent on the ligand substitution pattern. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12193 / 12196

页数：4

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