Possibilities of low-level determination of silicon in biological materials by activation analysis

被引:7
作者
Kucera, J [1 ]
Randa, Z [1 ]
机构
[1] Acad Sci Czech Republ, Inst Nucl Phys, CZ-25068 Rez, Czech Republic
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 2001年 / 370卷 / 2-3期
关键词
D O I
10.1007/s002160100802
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The capabilities of neutron and photon activation analysis (NAA and PAA, respectively) for low-level determination of silicon in biological materials have been examined. Sensitivities of a variety of modes of NAA and PAA with radiochemical separation have been evaluated. Results are presented for silicon in reference materials CSRM 12-2-03 Lucerne, Bowen's Kale, NIST SRM-1571 Orchard Leaves, and NIST SRM-1515 Apple Leaves. The results were obtained by employing the Si-29(n,p)Al-29 reaction with fast reactor neutrons and the radiochemical procedure developed for aluminium separation. Possibilities of further improvement of the silicon determination limit down to the mug g(-1) level by employing NAA and PAA with radiochemical separation are outlined.
引用
收藏
页码:241 / 245
页数:5
相关论文
共 17 条
[11]  
MANOKIN VN, 1987, TECHNICAL REPORT SER, V273, P305
[12]   TABLES OF NUCLEAR CONSTANTS FOR GAMMA-ACTIVATION ANALYSIS [J].
RANDA, Z ;
KREISINGER, F .
JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1983, 77 (02) :279-495
[13]   RADIOCHEMICAL NEUTRON-ACTIVATION METHOD FOR THE DETERMINATION OF SILICON AT MICROGRAM AND NANOGRAM LEVELS IN HIGH-PURITY MATERIALS [J].
SCHMID, W ;
KRIVAN, V .
ANALYTICAL CHEMISTRY, 1986, 58 (07) :1468-1471
[14]   DETERMINATION OF SILICON IN HIGH-PURITY METALS BY RADIOCHEMICAL NAA AND CPAA [J].
SCHMID, W ;
EGGER, KP ;
KRIVAN, V .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1988, 123 (02) :561-571
[15]  
SEGEBADE C, 1988, PHOTON ACTIVATION AN
[16]   ION-EXCHANGE GROUP-SEPARATION SCHEME FOR RAPID ANALYSIS OF COMPONENTS OF NEUTRON-ACTIVATED BIOLOGICAL TISSUES [J].
VELANDIA, JA ;
PERKONS, AK .
JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1974, 20 (02) :473-487
[17]   NEUTRON-ACTIVATION ANALYSIS TECHNIQUES FOR IDENTIFYING ELEMENTAL STATUS IN ALZHEIMERS-DISEASE [J].
WARD, NI ;
MASON, JA .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1987, 113 (02) :515-526