Molecular Rotors for the Detection of Chemical Warfare Agent Simulants

被引：86

作者：

Kim, Tae-Il ^{[1
]}

Maity, Shubhra Bikash ^{[1
]}

Bouffard, Jean ^{[2
]}

Kim, Youngmi ^{[1
]}

机构：

[1] Kyung Hee Univ, Dept Chem, 126 Kyungheedae Ro, Seoul 02447, South Korea

[2] Ewha Womans Univ, Dept Chem & Nano Sci BK Plus 21, 52 Ewhayeodae Gil, Seoul 03760, South Korea

来源：

ANALYTICAL CHEMISTRY | 2016年 / 88卷 / 18期

基金：

新加坡国家研究基金会;

关键词：

NERVE AGENTS; FLUOROGENIC DETECTION; FLUORESCENT SENSORS; MIMICS; PROBE; DYES; DISCRIMINATION; DCP;

D O I：

10.1021/acs.analchem.6b02516

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The fluorogenic probe o-OH is able to detect and quantify orgariop-hosphoms nerve agent mimics in solution and in the vapor phase following immobilization on a solid substrate, making the system a suitable candidate for the field detection of chemical warfare agents. Detection is achieved by the suppression of internal rotation upon phosphorylation of a reactive phenolate, resulting in a large fluorescence "turn-on" response.

引用

页码：9259 / 9263

页数：5

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