Molecular Rotors for the Detection of Chemical Warfare Agent Simulants

被引：86

作者：

Kim, Tae-Il ^{[1
]}

Maity, Shubhra Bikash ^{[1
]}

Bouffard, Jean ^{[2
]}

Kim, Youngmi ^{[1
]}

机构：

[1] Kyung Hee Univ, Dept Chem, 126 Kyungheedae Ro, Seoul 02447, South Korea

[2] Ewha Womans Univ, Dept Chem & Nano Sci BK Plus 21, 52 Ewhayeodae Gil, Seoul 03760, South Korea

来源：

ANALYTICAL CHEMISTRY | 2016年 / 88卷 / 18期

基金：

新加坡国家研究基金会;

关键词：

NERVE AGENTS; FLUOROGENIC DETECTION; FLUORESCENT SENSORS; MIMICS; PROBE; DYES; DISCRIMINATION; DCP;

D O I：

10.1021/acs.analchem.6b02516

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The fluorogenic probe o-OH is able to detect and quantify orgariop-hosphoms nerve agent mimics in solution and in the vapor phase following immobilization on a solid substrate, making the system a suitable candidate for the field detection of chemical warfare agents. Detection is achieved by the suppression of internal rotation upon phosphorylation of a reactive phenolate, resulting in a large fluorescence "turn-on" response.

引用

页码：9259 / 9263

页数：5

共 32 条

[1] Chemical approaches for detection and destruction of nerve agents
Ajami, Dariush
Rebek, Julius, Jr.
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (24) : 3936 - 3942
[2] Highly Selective Detection of Nerve-Agent Simulants with BODIPY Dyes
Barba-Bon, Andrea
Costero, Ana M.
Gil, Salvador
Harriman, Anthony
Sancenon, Felix
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (21) : 6339 - 6347
[3] Microbead chemical switches: An approach to detection of reactive organophosphate chemical warfare agent vapors
Bencic-Nagale, S
Sternfeld, T
Walt, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (15) : 5041 - 5048
[4] Molecular Rotors Based on the Boron Dipyrromethene Fluorophore
Benniston, Andrew C.
Harriman, Anthony
Whittle, Victoria. L.
Zelzer, Mischa
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (03) : 523 - 530
[5] Fluorescent Sensors for the Detection of Chemical Warfare Agents
Burnworth, Mark
Rowan, Stuart J.
Weder, Christoph
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (28) : 7828 - 7836
[6] A Rapid and Sensitive Strip-Based Quick Test for Nerve Agents Tabun, Sarin, and Soman Using BODIPY-Modified Silica Materials
Climent, Estela
Biyikal, Mustafa
Gawlitza, Kornelia
Dropa, Tomas
Urban, Martin
Costero, Ana M.
Martinez-Manez, Ramon
Rurack, Knut
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (32) : 11138 - 11142
[7] Chromo-Fluorogenic Detection of Nerve-Agent Mimics Using Triggered Cyclization Reactions in Push-Pull Dyes
Costero, Ana M.
Parra, Margarita
Gil, Salvador
Gotor, Raul
Mancini, Pedro M. E.
Martinez-Manez, Ramon
Sancenon, Felix
Royo, Santiago
[J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) : 1573 - 1585
[8] Fluorescent sensors for organophosphorus nerve agent mimics
Dale, TJ
Rebek, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (14) : 4500 - 4501
[9] Hydroxy Oximes as Organophosphorus Nerve Agent Sensors
Dale, Trevor J.
Rebek, Julius, Jr.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) : 7850 - 7852
[10] Fluorescent Discrimination between Traces of Chemical Warfare Agents and Their Mimics
Diaz de Grenu, Borja
Moreno, Daniel
Torroba, Tomas
Berg, Alexander
Gunnars, Johan
Nilsson, Tobias
Nyman, Rasmus
Persson, Milton
Pettersson, Johannes
Eklind, Ida
Wasterby, Par
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (11) : 4125 - 4128

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