Importance of dynamic hydrogen bonds and reorientation barriers in proton transport

被引：25

作者：

Nagamani, Chikkannagari ^{[2
]}

Viswanathan, Usha ^{[2
]}

Versek, Craig ^{[1
]}

Tuominen, Mark T. ^{[1
]}

Auerbach, Scott M. ^{[2
]}

Thayumanavan, S. ^{[2
]}

机构：

[1] Univ Massachusetts, Dept Phys, Amherst, MA 01003 USA

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 23期

关键词：

FUEL-CELL MEMBRANES; CONDUCTING POLYMERS; SOLID-STATE; ELECTROLYTE MEMBRANES; IMIDAZOLE; WATER; 1H-1,2,3-TRIAZOLE; NANOCHANNELS; COPOLYMERS; MECHANISM;

D O I：

10.1039/c1cc11207d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dynamic nature of hydrogen bonds in phenolic polymers, where the hydrogen bond donor/acceptor reorientation can occur in a single site, presents lower barriers for proton transport.

引用

页码：6638 / 6640

页数：3

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