The standard thermodynamic function of transfer of rubidium tetraphenylborate from water to straight-chain n-alkanols

被引：0

作者：

Li, DC ^{[1
]}

Wen, LX ^{[1
]}

Wang, Y ^{[1
]}

Liu, DJ ^{[1
]}

机构：

[1] Liaocheng Teachers Univ, Dept Chem, Liaocheng 252059, Peoples R China

来源：

ACTA CHIMICA SINICA | 1998年 / 56卷 / 09期

关键词：

RbBPh4; solubility; standard transfer thermodynamic function; activity coefficient; ionic association;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solubilities of RbBPh4 in water, methanol, ethanol, 1 - propanol, 1 - butanol, 1 pentanol, 1 - hexanol, 1 - hepanol and 1 - octanol at 288. 15 similar to 328. 15K have been determined by spectrophotometry. The standard transfer thermodynamic function of RbBPh4 from water to straight- chain alkanols at 288. 15 similar to 328. 15K has been calculated. The results can be experssed as Delta<INF>tr</INF>G<INF>w-->s</INF>degrees= -20.3504 + 6.6005x10-5T2+ 14.6628 1gn/1-7.7713x10-9T3 Delta<INF>tr</INF>S<INF>w-->s</INF>degrees= -0.1329T - 3.4185x10-4T2 1gn/(1 - 7.7713x10-9T3)2 Furthermore, the contribution of microscopic interaction to the standard Gibbs energy of transfer of RbBPh4 was calculated and discussed.

引用

页码：859 / 866

页数：8

共 16 条

[1] AMOTT S, 1958, ACTA CRYSTALLOGR, V11, P449
[2] BERNE PM, 1983, J CHEM ENG DATA, V28, P316
[3] FREE-ENERGIES OF TRANSFER OF SOME SINGLE IONS FROM ETHYLENE-GLYCOL TO ITS ISODIELECTRIC MIXTURES WITH ACETONITRILE AT 25-DEGREES-C
BOSE, K
KUNDU, KK
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (18): : 2476 - 2481
[4] BOSE K, 1979, INDIAN J CHEM, V1, P122
[5] THERMODYNAMIC PROPERTIES OF NONAQUEOUS SOLUTIONS .4. FREE ENERGIES AND ENTROPIES OF SOLVATION OF SOME ALKALI METAL HALIDES IN N,N-DIMETHYLFORMAMIDE
CRISS, CM
LUKSHA, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (08): : 2966 - &
[6] IONIC ASSOCIATION .3. THE EQUILIBRIUM BETWEEN ION PAIRS AND FREE IONS
FUOSS, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (19) : 5059 - 5061
[7] CRITICAL-STUDY OF THE PH4ASPH4B ASSUMPTION FOR SINGLE ION THERMODYNAMICS IN AMPHIPROTIC AND DIPOLAR-APROTIC SOLVENTS - EVALUATION OF PHYSICAL PARAMETERS RELEVANT TO THEORETICAL CONSIDERATION
KIM, JI
[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1978, 113 (02): : 129 - 150
[8] SCALED PARTICLE THEORY OF AQUEOUS AND NON-AQUEOUS SOLUTIONS
PIEROTTI, RA
[J]. CHEMICAL REVIEWS, 1976, 76 (06) : 717 - 726
[9] ESTIMATION OF MEDIUM EFFECTS FOR SINGLE IONS AND THEIR ROLE IN INTERPRETATION OF NONAQUEOUS PH
POPOVYCH, O
[J]. ANALYTICAL CHEMISTRY, 1966, 38 (04) : 558 - &
[10] SOLUBILITIES OF POTASSIUM TRIISOAMYLBUTYLAMMONIUM AND TETRABUTYLAMMONIUM TETRAPHENYLBORIDES AND PICRATES IN WATER AND METHANOL AND THEIR MEDIUM EFFECTS AT 25 DEGREES
POPOVYCH, O
FRIEDMAN, RM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (05): : 1671 - &

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