Thermal Properties, Conductivity, and Spin-lattice Relaxation of Gel Electrolyte Based on Low Molecular Weight Gelator and Solution of High Temperature Ionic Liquid

被引:19
作者
Bielejewski, Michal [1 ]
Puszkarska, Anna [1 ]
Tritt-Goc, Jadwiga [1 ]
机构
[1] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland
关键词
high temperature ionic liquid; low molecular weight gelator; gel electrolytes; thermal properties; enhanced ionic conductivity; spin-lattice relaxation; FIELD-CYCLING NMR; SENSITIZED SOLAR-CELLS; GLUCOFURANOSE DERIVATIVES; SUPRAMOLECULAR GELATORS; ORGANIC-SOLVENTS; SUGAR; ABILITY; WATER; ORGANOGELATORS; PERFORMANCE;
D O I
10.1016/j.electacta.2015.03.009
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Gel electrolyte based on low molecular weight organic gelator methyl-4,6-O-(p-nitrobenzylidene)-alpha-D-glucopyranoside was formed by the self-assembly phenomena in aqueous solution of high temperature ionic liquid tetramethylammonium bromide. The solidification process was based on sol-gel technique with controlled gelation temperature. When the temperature was below the characteristic gel-sol phase transition temperature, T-gs, the gel electrolyte was solid-like. The gel electrolytes showed enhanced ionic conductivity to those of the pure electrolyte in liquid state in whole temperature range below T-gs. The thermal stability, ionic conductivity and molecular dynamics investigated as a function of temperature and concentration of the gelator, together with the gel microstructure were performed to get some insight in to the origin of the enhanced conductivity properties. Intermolecular interaction between ion complexes and gelator aggregates was implicated by the data obtained and suggested as the origin of the conductivity enhancement effect. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:122 / 129
页数:8
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