Developing remote metal binding sites in heteropolymolybdates

被引：172

作者：

Marcoux, PR ^{[1
]}

Hasenknopf, B ^{[1
]}

Vaissermann, J ^{[1
]}

Gouzerh, P ^{[1
]}

机构：

[1] Univ Paris 07, CNRS, UMR 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 13期

关键词：

polyoxometalates; molybdenum; N ligands; coordination chemistry;

D O I：

10.1002/ejic.200200677

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anderson-type polyoxomolybdates [MMO6O18{(OCH2)(3)-CNH2}(2)](3-) (M = Mn-III, Fe-III) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = Ni-II or Zn-II are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese-containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono- and bidentate binding sites for metal cations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：2406 / 2412

页数：7

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