Charge-transfer complexes between iodine and substituted thioureas: Determination of thermodynamic and spectroscopic properties

被引：1

作者：

Fooken, C ^{[1
]}

Baumann, W ^{[1
]}

机构：

[1] UNIV MAINZ,INST PHYS CHEM,D-55099 MAINZ,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1996年 / 51卷 / 1-2期

关键词：

D O I：

10.1515/zna-1996-1-217

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

15 iodine complexes with substituted thioureas were investigated in dichloromethane solution by UV-visible spectroscopy, and their equilibrium constants, reaction enthalpies and molar absorption coefficients were determined. The influence of the substituents on the properties of the charge-transfer complexes is examined. A critical discussion of previously published data is given, where comparable data are available.

引用

页码：116 / 122

页数：7

共 16 条

[1] The magnitude of the solvent effect in dipole-moment measurements Part VI Induced and mesomeric moments of the alkyl halides and the halogenobenzenes [J].