High-pressure Raman spectroscopy study of 1-fluoro-2,4-dinitrobenzene

被引：1
|
作者：
Hebert, P [1 ]
Gaillard, C [1 ]
Simonetti, P [1 ]
机构：
[1] CEA Le Ripault, F-37260 Monts, France
来源：
HIGH PRESSURE RESEARCH | 2003年 / 23卷 / 03期
关键词：
DNFB; energetic materials; phase diagram; Raman spectroscopy;
D O I：
10.1080/0895795032000102397
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The high pressure and high temperature behavior of the energetic molecule 1-fluoro-2,4-dinitrobenzene (DNFB) was studied by Raman spectroscopy in a Diamond Anvil Cell (DAC). The pressure-temperature phase diagram was determined up to 20 GPa and 550 K (thermal decomposition). Between 0 and 15 GPa, two solid-solid phase transitions were suggested from slope changes of the vibrational modes. Above 15 GPa, irreversible chemical transformation was observed.
引用
收藏
页码：235 / 238
页数：4
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