Structure determination and modeling of monoclinic trioctylphosphine oxide

被引：20

作者：

Doan-Nguyen, Vicky V. T. ^{[1
]}

Carroll, Patrick J. ^{[2
]}

Murray, Christopher B. ^{[1
,2
]}

机构：

[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA

[2] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2015年 / 71卷

关键词：

trioctylphosphine oxide; TOPO; crystal structure; nanocrystal synthesis; ligand stabilizer; phosphorus source; CDSE;

D O I：

10.1107/S2053229615003009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trioctylphosphine oxide (TOPO), C24H51OP, was recrystallized from ambient evaporation in acetone. TOPO single crystals form with a monoclinic P2(1)/c structure. Fourier transform IR (FT-IR) spectroscopy captures the characteristic stretching modes from the seven methylene groups, the phosphoryl P=O bond, and the phosphoryl-carbon bond.

引用

页码：239 / +

页数：7

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