Structure determination and modeling of monoclinic trioctylphosphine oxide

被引:19
作者
Doan-Nguyen, Vicky V. T. [1 ]
Carroll, Patrick J. [2 ]
Murray, Christopher B. [1 ,2 ]
机构
[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2015年 / 71卷
关键词
trioctylphosphine oxide; TOPO; crystal structure; nanocrystal synthesis; ligand stabilizer; phosphorus source; CDSE;
D O I
10.1107/S2053229615003009
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trioctylphosphine oxide (TOPO), C24H51OP, was recrystallized from ambient evaporation in acetone. TOPO single crystals form with a monoclinic P2(1)/c structure. Fourier transform IR (FT-IR) spectroscopy captures the characteristic stretching modes from the seven methylene groups, the phosphoryl P=O bond, and the phosphoryl-carbon bond.
引用
收藏
页码:239 / +
页数:7
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