Aqueous rechargeable lithium battery (ARLB) based on LiV3O8 and LiMn2O4 with good cycling performance

被引：139
作者：
Wang, G. J.
Zhang, H. P.
Fu, L. J.
Wang, B.
Wu, Y. P. [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 08期
关键词：
aqueous rechargeable lithium battery (ARLB); LiMn2O4; LiV3O8; cycle life;
D O I：
10.1016/j.elecom.2007.04.017
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Crystalline LiV3O8 and LiMn2O4 were prepared by conventional solid-state reaction and characterized by X-ray diffraction analysis. Cyclic voltammetry technique was employed to evaluate the electrochemical behaviors of LiV3O8 and LiMn2O4 in 2 mol/l LiSO4 aqueous solution, and the results show that both LiV3O8 and LiMn2O4 are very stable in this aqueous electrolyte and can be used as the negative and positive electrode material without evident hydrogen or oxygen evolution. An aqueous rechargeable lithium battery (ARLB) was fabricated by using the above two intercalation compounds as the negative and positive electrodes. This battery exhibits good cycling behavior and the average discharge voltage is about 1.04 V. (c) 2007 Elsevier B.V. All rights reserved.
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页码：1873 / 1876
页数：4
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