Reduction of phosphine oxides to the corresponding phosphine derivatives in Mg/Me3SiCl/DMI system

被引：15

作者：

Kuroboshi, Manabu ^{[1
]}

Kita, Toshihito ^{[1
]}

Aono, Asuka ^{[1
]}

Katagiri, Toshimasa ^{[1
]}

Kikuchi, Seiya ^{[1
]}

Yamane, Syoko ^{[1
]}

Kawakubo, Hiromu ^{[2
]}

Tanaka, Hideo ^{[1
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan

[2] Nihon Pharmaceut Univ, Saitama 3520805, Japan

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 07期

关键词：

Reduction; Phosphine oxide; Phosphine; Magnesium; 1,3-Dimethy1-2-imidazolidinone; TRIPHENYLPHOSPHINE OXIDE; TERTIARY; EFFICIENT; SECONDARY; LIGANDS; VERBINDUNGEN; CONVENIENT; RESOLUTION; REAGENT; BINAP;

D O I：

10.1016/j.tetlet.2014.12.132

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct reductions of phosphine oxides to the corresponding phosphines were performed successfully by using Mg/Me3SiCl/DMI system. The reduction proceeded under mild conditions and was applicable to a wide range of phosphine oxides; triarylphosphine oxides, alkyldiarylphosphine oxides, and dialkylarylphosphine oxides gave the corresponding phosphines in good to excellent yields. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：918 / 920

页数：3

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