A new 2D silver(I) inorganic -organic hybrid constructed from in situ decarboxylation reaction: Synthesis, structure and properties

被引：2

作者：

Yu, Xiao-Yang ^{[1
]}

Li, Sheng-Ling ^{[1
]}

Zhang, Rui ^{[1
]}

Gao, Lu ^{[2
]}

Lu, Tong ^{[2
]}

Cao, Xue-Ling ^{[1
]}

Cui, Hao ^{[1
]}

Shi, Zhenyu ^{[3
]}

Zheng, Yuguo ^{[3
]}

Yang, Ying ^{[1
]}

机构：

[1] Jilin Inst Chem Technol, Jilin 132022, Jilin, Peoples R China

[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[3] Xingyi Normal Univ Nationalities, Key Lab Chem Synth & Environm Pollut Control Reme, Xingyi 562400, Guizhou, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2020年 / 510卷

基金：

美国国家科学基金会;

关键词：

HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; ANTIBACTERIAL; MOLYBDATE; CLUSTERS; LIGANDS; CHEMISTRY; FRAMEWORK; GROWTH;

D O I：

10.1016/j.ica.2020.119717

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A polyoxometalate-based inorganic-organic hybrid, [Ag(Hpi)(Mo3O10)] (1) (pi = 2-(pyridine-3-yl)-1H-imidazole), has been synthesized and characterized. In 1, adjacent [Mo3O10]2− chains are linked by Ag+ to form a 2D layer structure. The organic ligand pi is formed through hydrothermal in situ decarboxylation reaction of H2pidc (H2pidc = 2-(pyridine-3-yl)-1H-imidazole-4,5-dicarboxylic acid). The luminescence property, photocatalytic activity and antibacterial activity were also investigated. © 2020 Elsevier B.V.

引用

页数：5

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