Phase control studies in Gd5Si2Ge2 giant magnetocaloric compound

被引：25

作者：

Belo, J. H. ^{[1
,2
]}

Pereira, A. M. ^{[1
,2
]}

Ventura, J. ^{[1
,2
]}

Oliveira, G. N. P. ^{[1
,2
]}

Araujo, J. P. ^{[1
,2
]}

Tavares, P. B. ^{[3
,4
]}

Fernandes, L. ^{[3
,4
]}

Algarabel, P. A. ^{[5
,6
]}

Magen, C. ^{[7
]}

Morellon, L. ^{[5
,6
,8
]}

Ibarra, M. R. ^{[5
,6
,8
]}

机构：

[1] Univ Porto, IFIMUP, P-4169007 Oporto, Portugal

[2] Univ Porto, Fac Ciencias, Dept Fis & Astron, IN Inst Nanosci & Nanotechnol, P-4169007 Oporto, Portugal

[3] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001801 Vila Real, Portugal

[4] Univ Tras Os Montes & Alto Douro, CQ VR, P-5001801 Vila Real, Portugal

[5] Univ Zaragoza, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

[6] CSIC, E-50009 Zaragoza, Spain

[7] Univ Zaragoza, Inst Nanociencia Aragon ARAID, E-50009 Zaragoza, Spain

[8] Univ Zaragoza, Inst Nanociencia Aragon, E-50009 Zaragoza, Spain

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2012年 / 529卷

关键词：

Magnetocaloric compounds; Formation and annealing; Crystallographic aspects of phase transitions; Magnetic phase transitions; MAGNETIC ENTROPY CHANGE; GD-5(SIXGE1-X)(4); FEATURES; ALLOYS;

D O I：

10.1016/j.jallcom.2012.02.164

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A systematic set of annealings on arc-melted synthesized Gd5Si2Ge2 sample was performed. Through powder X-ray diffraction (XRD) and magnetometry measurements we monitored the effect of varying the annealing time with constant temperature (T = 1473 K) on the formation of the monoclinic (M) crystallographic phase fraction, which is the one responsible for the giant magnetocaloric effect (GMCE) in this compound. The conversion of the orthorhombic O(I) crystallographic phase into M was achieved, resulting in a significant increase of the M mass fraction. Such conversion led to a change in the magnetic transition nature, evolving from a second to a first order transition for the as-cast and annealed samples, respectively. An optimal annealing time range for the M phase conversion was identified to be within 80-120 min at T = 1473 K followed by a rapid quenching to liquid N-2. Furthermore, an increase up to similar to 50% of the magnetocaloric effect was obtained for the sample annealed during 120 min. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：89 / 95

页数：7

共 41 条

[1] CRITERION FOR FERROMAGNETISM FROM OBSERVATIONS OF MAGNETIC ISOTHERMS
ARROTT, A
[J]. PHYSICAL REVIEW, 1957, 108 (06): : 1394 - 1396
[2] Magnetic properties of Gd5T3 intermetallic compounds (T=Si,Ge,Sn)
Canepa, F
Cirafici, S
Napoletano, M
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 335 (1-2) : L1 - L4
[3] On the determination of the magnetic entropy change in materials with first-order transitions
Caron, L.
Ou, Z. Q.
Nguyen, T. T.
Thanh, D. T. Cam
Tegus, O.
Bruck, E.
[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (21) : 3559 - 3566
[4] Linear microstructural features in R5(Si,Ge)4-type alloys:: Difficulties in identification
Chumbley, L. S.
Ugurlu, O.
McCallum, R. W.
Dennis, K. W.
Mudryk, Y.
Gschneidner, K. A., Jr.
Pecharsky, V. K.
[J]. ACTA MATERIALIA, 2008, 56 (03) : 527 - 536
[5] The effect of low temperature annealing on the structure of Gd5Si2Ge2 alloy
Fu, H.
Zu, X. T.
He, X.
He, W. S.
Shen, T. D.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 431 (1-2) : 89 - 92
[6] MAGNETIC-PROPERTIES OF SOME RARE-EARTH SILICIDES - GDSI, GD5SI3, DY5-XNDXSI3
GANAPATHY, EV
KUGIMIYA, K
STEINFINK, H
TCHERNEV, DI
[J]. JOURNAL OF THE LESS-COMMON METALS, 1976, 44 (JAN): : 245 - 258
[7] Gokhale A.B., 1989, Bull. Alloy Phase Diagr, V10, P147
[8] Gorbachuk NP, 2001, POWDER METALL MET C+, V40, P54
[9] Recent developments in magnetocaloric materials
Gschneidner, KA
Pecharsky, VK
Tsokol, AO
[J]. REPORTS ON PROGRESS IN PHYSICS, 2005, 68 (06) : 1479 - 1539
[10] Estimation of second order phase transition temperature of the orthorhombic phase of Gd5(SixGe1-x)4 using Arrott plots
Hadimani, R. L.
Melikhov, Y.
Snyder, J. E.
Jiles, D. C.
[J]. JOURNAL OF APPLIED PHYSICS, 2008, 103 (03)

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