Porous anode of lithium-oxygen battery based on double-gas-path structure

被引:16
作者
Cai, Kedi [1 ]
Xiao, Yao [1 ]
Lang, Xiaoshi [1 ]
Tong, Yujin [2 ]
He, Tieshi [1 ]
Mao, Zhiming [4 ]
Wang, Cheng [3 ]
机构
[1] Bohai Univ, Liaoning Engn Technol Res Ctr Supercapacitor, Jinzhou 121013, Peoples R China
[2] Max Planck Gesell, Fritz Haber Inst, Interfacial Mol Spect Grp, D-14195 Berlin, Germany
[3] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
[4] Beijing Sino Hydrogen Technol Co Ltd, Beijing 100084, Peoples R China
关键词
Lithium-oxygen battery; Porous anode; Double-gas-path; Lithium protection; Dynamic equilibrium; LI METAL ANODE; AIR BATTERIES; HIGH-CAPACITY; ELECTROLYTE; PERFORMANCE; CATHODE;
D O I
10.1016/j.ijhydene.2017.06.114
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A lithium-oxygen battery of double-gas-path structure and porous anode is presented in this work. Different from traditional structure battery, porous anode and the gas channel of anode side are used to provide argon gas for the battery. In order to protect the anode from corrosion of oxygen which penetrates from the cathode to the anode by dynamic gas-phase equilibrium. The improvement of the battery performance is attributed to the novel structure that can protect lithium metal from the corrosion of oxygen and it also reduces the growth of dendrite. The lithium-oxygen battery based on double-gas-path structure shows long cycle life (38 cycles), high discharge specific capacity (2510 mAh g(-1)) and specific energy density (7200 W h kg(-1)). More importantly, this work will also provide new ideas and methods for the research of other metal-air battery. (C) 2017 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.
引用
收藏
页码:29944 / 29948
页数:5
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