A novel and recyclable catalytic system for propylene carbonate synthesis from propylene oxide and CO2

被引：30

作者：

Wang, Zhiqiang ^{[1
]}

Bu, Zhanwei ^{[1
]}

Cao, Tingting ^{[1
]}

Ren, Tiegang ^{[1
]}

Yang, Lirong ^{[1
]}

Li, Weijie ^{[1
]}

机构：

[1] Henan Univ, Res Inst Fine Chem Engn, Kaifeng 475004, Henan, Peoples R China

来源：

POLYHEDRON | 2012年 / 32卷 / 01期

关键词：

Zinc complex; Propylene carbonate; Carbon dioxide; Propylene oxide; Catalyst; CYCLIC CARBONATES; CHEMICAL FIXATION; DIOXIDE; COMPLEX; TRANSFORMATION; KINETICS;

D O I：

10.1016/j.poly.2011.07.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel and recyclable catalytic system composed of Zn[bis(2-hydroxybenzene)phthaldimine] [Zn(BHBPDI)] and tetrabutylammonium bromide (TBAB) was developed to catalyze the coupling reaction of CO2 and propylene oxide to yield the cyclic carbonate. The different parameters had been investigated. Nearly 100% selectivity and 100% yield of propylene carbonate was achieved under the optimized reaction conditions. The [Zn(BHBPDI)] could be easily recovered and reused for many times. The activity of the catalytic system decreased obviously after nine recycles, but the activity was restored by adding an amount of TBAB to the reaction mixture. On the basis of the experimental results, the mechanism for the reaction was proposed. (c) 2011 Elsevier Ltd. All rights reserved.

引用

页码：86 / 89

页数：4

共 23 条

[1] Spectroscopic study of molecular structures of novel Schiff base derived from o-phthaldehyde and 2-aminophenol and its coordination compounds together with their biological activity
Abdallah, Sayed M.
Mohamed, Gehad G.
Zayed, M. A.
Abou El-Ela, Mohsen S.
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 73 (05) : 833 - 840
[2] A ruthenium complex exhibiting high catalytic efficiency for the formation of propylene carbonate from carbon dioxide
Bu, Zhanwei
Qin, Gang
Cao, Shaokui
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 277 (1-2) : 35 - 39
[3] Synthesis of propylene carbonate from carbon dioxide using trans-dichlorotetrapyridineruthenium(II) as catalyst
Bu, Zhanwei
Wang, Zhiqiang
Yang, Lirong
Cao, Shaokui
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (11) : 813 - 816
[4] Cyclic Carbonate Synthesis Catalysed by Bimetallic Aluminium-Salen Complexes
Clegg, William
Harrington, Ross W.
North, Michael
Pasquale, Riccardo
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (23) : 6828 - 6843
[5] The direct transformation of carbon dioxide to organic carbonates over heterogeneous catalysts
Dai, Wei-Li
Luo, Sheng-Lian
Yin, Shuang-Feng
Au, Chak-Tong
[J]. APPLIED CATALYSIS A-GENERAL, 2009, 366 (01) : 2 - 12
[6] Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides
Decortes, Antonello
Castilla, Ana M.
Kleij, Arjan W.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (51) : 9822 - 9837
[7] Cycloaddition of CO2 to Epoxides Using a Highly Active Co(III) Complex of Tetraamidomacrocyclic Ligand
Ghosh, Anindya
Ramidi, Punnamchandar
Pulla, Sharon
Sullivan, Shane Z.
Collom, Samuel L.
Gartia, Yashraj
Munshi, Pradip
Biris, Alexandru S.
Noll, Bruce C.
Berry, Brian C.
[J]. CATALYSIS LETTERS, 2010, 137 (1-2) : 1 - 7
[8] A DFT Study on the Mechanism of the Coupling Reaction between Chloromethyloxirane and Carbon Dioxide Catalyzed by Re(CO)5Br
Guo, Cai-Hong
Song, Jiang-Yu
Jia, Jian-Feng
Zhang, Xian-Ming
Wu, Hai-Shun
[J]. ORGANOMETALLICS, 2010, 29 (09) : 2069 - 2079
[9] Influence of poles and polar linkings on the course pursued by elimination reactions Part XVI Mechanism of the thermal decomposition of quaternary ammonium compounds
Hughes, ED
Ingold, CK
Patfl, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1933, : 526 - 530
[10] Kim HS, 2000, ANGEW CHEM INT EDIT, V39, P4096, DOI 10.1002/1521-3773(20001117)39:22<4096::AID-ANIE4096>3.3.CO

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