Self-assembly and Characterization of TiO2/PS Complex Particle and TiO2 Hollow Spheres

被引:0
作者
Xiao, Fan [1 ]
Li, Wei [1 ]
Zhang, Zhixian [1 ]
Gao, Fei [1 ]
机构
[1] Zhejiang Univ Technol, Inst Mat & Surface Engn, Hangzhou 310014, Zhejiang, Peoples R China
来源
NEW AND ADVANCED MATERIALS, PTS 1 AND 2 | 2011年 / 197-198卷
关键词
TiO2/PS; TiO2 Hollow Spheres; Self-assembly; pH; PEROXIDE;
D O I
10.4028/www.scientific.net/AMR.197-198.136
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
Using TiO2 particles obtained by hydrolysis of titanium oxysulfate as the precursor, polystyrene (PS) microspheres as the template, TiO2/PS complex particles were successfully deposited on Ti substrates through layer-by-layer self-assembly technique and the surfactant-assisted process at low temperature. Then removed PS spheres by two methods, TiO2 hollow spheres were attained. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to characterize the synthesized materials. The results showed that the crystallization, structure and surface morphology of TiO2/PS on the surface have a great relationship with the pH value of treating solution. Diversity effects on surface integrity and bioactive of hollow spheres happened due to different ways of removing PS core.
引用
收藏
页码:136 / 139
页数:4
相关论文
共 7 条
[1]   THE THERMAL STABILITY OF HYDRATED TITANIUM PEROXIDE AND OF SOME PEROXY TITANIUM COMPOUNDS [J].
JERE, GV ;
PATEL, CC .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 20 (3-4) :343-344
[2]   Study on the influence of heat treatment on the crystallographic phases of nanostructured TiO2 films [J].
Kuznetsova, I. N. ;
Blaskov, V. ;
Znaidi, L. .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2007, 137 (1-3) :31-39
[3]   Enhanced in vitro apatite-forming ability of sol-gel derived titania films by ultraviolet irradiation [J].
Shozui, T. ;
Tsuru, K. ;
Hayakawa, S. ;
Osaka, A. .
BIOCERAMICS, VOL 20, PTS 1 AND 2, 2008, 361-363 :601-604
[4]  
Song XQ, 2006, ACTA CHIM SINICA, V64, P198
[5]   Preparation of TiO2/PS complex nanoparticles [J].
Su, Bitao ;
Ma, Zhanying ;
Min, Shixiong ;
She, Shixiong ;
Wang, Zhiyuan .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 458 (1-2) :44-47
[6]   In vitro apatite deposition on titania film derived from chemical treatment of Ti substrates with an oxysulfate solution containing hydrogen peroxide at low temperature [J].
Xiao, F ;
Tsuru, K ;
Hayakawa, S ;
Osaka, A .
THIN SOLID FILMS, 2003, 441 (1-2) :271-276
[7]   Preparation of porous TiO2/Ti composite membrane for immunoisolation [J].
Zhan Minjing ;
Li Gang ;
Wei Qiang ;
Cui Hualei ;
Lin Ling .
APPLIED SURFACE SCIENCE, 2008, 255 (05) :2256-2258