Bidentate ligands capable of variable bond angles in the self-assembly of discrete supramolecules

被引：36

作者：

Chi, KW ^{[1
]}

Addicott, C ^{[1
]}

Arif, AM ^{[1
]}

Das, N ^{[1
]}

Stang, PJ ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 25期

关键词：

D O I：

10.1021/jo0353785

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Flexible donor ligands like 1,2-bis(3-pyridyl)ethyne or 1,4-bis(3-pyridyl)-1,3-butadiyne self-assemble into discrete supramolecules instead of infinite networks upon combination with organoplatinum 90, 120, and 180 degree acceptor units. These systems are unique examples of versatile pyridine donors adjusting their bonding directionality to accommodate rigid platinum acceptors in the formation of closed macrocycles.

引用

页码：9798 / 9801

页数：4

共 22 条

[1] Baxter P. N. W., 1996, COMPREHENSIVE SUPRAM, V9, P165
[2] Supermolecules by design
Caulder, DL
Raymond, KN
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 975 - 982
[3] The rational design of high symmetry coordination clusters
Caulder, DL
Raymond, KN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08): : 1185 - 1200
[4] An improved preparation of 4-ethynylpyridine and its application to the synthesis of linear bipyridyl ligands
Champness, NR
Khlobystov, AN
Majouga, AG
Schröder, M
Zyk, NV
[J]. TETRAHEDRON LETTERS, 1999, 40 (29) : 5413 - 5416
[5] Supramolecular arrays based on dimetal building units
Cotton, FA
Lin, C
Murillo, CA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (10) : 759 - 771
[6] Metal-directed self-assembly of two- and three-dimensional synthetic receptors
Fujita, M
[J]. CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) : 417 - 425
[7] Molecular paneling via coordination
Fujita, M
Umemoto, K
Yoshizawa, M
Fujita, N
Kusukawa, T
Biradha, K
[J]. CHEMICAL COMMUNICATIONS, 2001, (06) : 509 - 518
[8] Holliday BJ, 2001, ANGEW CHEM INT EDIT, V40, P2022, DOI 10.1002/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO
[9] 2-D
[10] Self-assembly of discrete cyclic nanostructures mediated by transition metals
Leininger, S
Olenyuk, B
Stang, PJ
[J]. CHEMICAL REVIEWS, 2000, 100 (03) : 853 - 907

← 1 2 3 →