Electrolytically fabricated nickel microrods on screen printed graphite electrodes: Electro-catalytic oxidation of alcohols

被引：9

作者：

Choudhry, Nadeem A. ^{[1
]}

Banks, Craig E. ^{[1
]}

机构：

[1] Manchester Metropolitan Univ, Sch Chem & Environm, Fac Sci & Engn, Div Chem & Environm Sci, Manchester M1 5GD, Lancs, England

来源：

ANALYTICAL METHODS | 2011年 / 3卷 / 01期

关键词：

D O I：

10.1039/c0ay00527d

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Nickel modified graphite screen printed electrodes are explored towards the sensing of alcohols in alkaline solutions. Electrolytically formed nickel microrods with average lengths and diameters of 12 mu M and 2 mu M respectively are shown to be readily formed on the surfaces of graphite screen printed electrodes. This is the first example of electrolytically formed nickel nanorods which exhibit electro-catalysis towards the sensing of ethanol over the range 2.6-23 mM and glycol over the range 230-1840 mu M with limits of detection of 1.4 mM and 186 mu M respectively.

引用

页码：74 / 77

页数：4

共 25 条

[1] OXIDATION OF ALCOHOLS AT A NICKEL ANODE IN ALKALINE TERT-BUTANOL-WATER MIXTURES [J].

AMJAD, M ;

PLETCHER, D ;

SMITH, C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1977, 124 (02) :203-206

[2] Alkaline direct alcohol fuel cells [J].

Antolini, E. ;

Gonzalez, E. R. .

JOURNAL OF POWER SOURCES, 2010, 195 (11) :3431-3450

[3] Catalysts for direct ethanol fuel cells [J].

Antolini, Ermete .

JOURNAL OF POWER SOURCES, 2007, 170 (01) :1-12

[4]

BRETT CMA, 1998, ELECTROANAL, P81

[5] Determination of lamotrigine by adsorptive stripping voltammetry using silver nanoparticle-modified carbon screen-printed electrodes [J].

Calvo, M. Encarnacion Burgoa ;

Renedo, Olga Dominguez ;

Martinez, A. Julia Arcos .

TALANTA, 2007, 74 (01) :59-64

[6] Disposable highly ordered pyrolytic graphite-like electrodes: Tailoring the electrochemical reactivity of screen printed electrodes [J].

Choudry, Nadeem A. ;

Kampouris, Dimitrios K. ;

Kadara, Rashid O. ;

Banks, Craig E. .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (01) :6-9

[7] OXIDATION OF ORGANIC COMPOUNDS AT A NICKEL ANODE IN ALKALINE SOLUTION [J].

FLEISCHMANN, M ;

KORINEK, K ;

PLETCHER, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1971, 31 (01) :39-+

[8] Graphite screen printed electrodes for the electrochemical sensing of chromium(VI) [J].

Hallam, Philip M. ;

Kampouris, Dimitrios K. ;

Kadara, Rashid O. ;

Banks, Craig E. .

ANALYST, 2010, 135 (08) :1947-1952

[9] SCREEN-PRINTED VOLTAMMETRIC AND AMPEROMETRIC ELECTROCHEMICAL SENSORS FOR DECENTRALIZED TESTING [J].

HART, JP ;

WRING, SA .

ELECTROANALYSIS, 1994, 6 (08) :617-624

[10]

Honeychurch KC, 2000, ELECTROANAL, V12, P171, DOI 10.1002/(SICI)1521-4109(200002)12:3<171::AID-ELAN171>3.0.CO

← 1 2 3 →