The improved synthesis of [Cr(N)(salen)].CH3NO2

被引：10

作者：

Bendix, J

Wilson, SR

Prussak-Wieckowska, T

机构：

[1] Univ Copenhagen, Dept Chem, Lab 1, DK-2100 Copenhagen, Denmark

[2] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198000870

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, {2,2'-[1,2- ethanediylbis(nitrilomethylidyne)]diphenolato-O,N,N',O'}nitridochromium(V) nitromethane solvate, [Cr(N)(C16H14N2O2)].-CH3NO2, the metal center is five-coordinated. The chromium-nitride bond length is 1.559(2) Angstrom, which is 0.04 Angstrom longer than in the analogous manganese(V) compound. The structure contains a co-crystallized nitromethane molecule, In line with its accepted weak donor properties, this solvent molecule does not interact with the coordinatively unsaturated metal center.

引用

收藏

页码：923 / 925

页数：3

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