An efficient electrochemical synthesis of β-keto sulfones from sulfinates and 1,3-dicarbonyl compounds

被引:42
|
作者
Pan, Xiao-Jun [1 ]
Gao, Jian [1 ]
Yuan, Gao-Qing [1 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrosynthesis; beta-Keto sulfones; Sulfinates; 1,3-Dicarbonyl compounds; POLYSUBSTITUTED OXAZOLES; IODINE; TRANSFORMATION; SULFONYLATION; CYCLIZATION; INHIBITORS; CONVERSION; INDOLES; ACIDS; DMSO;
D O I
10.1016/j.tet.2015.06.063
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient electrochemical synthesis of beta-keto sulfones from sulfinates and 1,3-dicarbonyl compounds has been developed. The present electrochemical route could afford the target products in high to excellent yields under mild conditions. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5525 / 5530
页数:6
相关论文
共 50 条
  • [41] Iridium(III)-Catalyzed C-H Functionalization of Triarylphosphine Oxides with Diazo Dicarbonyl Compounds: Synthesis of α-Aryl 1,3-Dicarbonyl Derivatives
    Lou, Qin-Xin
    Li, Jing-Yu
    Yang, Shang-Dong
    SYNLETT, 2021, 32 (13) : 1365 - 1370
  • [42] An efficient synthesis of pentasubstituted pyrroles: one-pot four-component reaction of arylamine, acetylenedicarboxylate, arylglyoxal, and symmetrical 1,3-dicarbonyl compounds
    Mehrabi, Hossein
    Alizadeh-Bami, Farzaneh
    Ranjbar-Karimi, Reza
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2018, 15 (09) : 1961 - 1967
  • [43] Sequential gold-catalyzed reactions of 1-phenylprop-2-yn-1-ol with 1,3-dicarbonyl compounds
    Arcadi, Antonio
    Alfonsi, Maria
    Chiarini, Marco
    Marinelli, Fabio
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (04) : 576 - 582
  • [44] Electrochemical Synthesis of β-Keto Sulfones from Enol Acetates and Sulfonyl Hydrazides
    Yang, Zhiqi
    Xing, Jiaxin
    Xu, Yingli
    Wang, Junjie
    Zhou, Pengcheng
    JOURNAL OF ORGANIC CHEMISTRY, 2025, 90 (13): : 4488 - 4494
  • [45] Cyclohexenones Through Regioselective Addition of 1,3-Dicarbonyl Compounds to Terpenoid-Like Bischalcones
    Findik, Esra
    Budak, Yakup
    Ceylan, Mustafa
    SYNTHETIC COMMUNICATIONS, 2009, 39 (20) : 3647 - 3656
  • [46] Synthesis of 1,2,3,5-tetrasubstituted pyrrole derivatives from 2-(2-bromoallyl)-1,3-dicarbonyl compounds
    Demir, AS
    Akhmedov, IM
    Sesenoglu, O
    TETRAHEDRON, 2002, 58 (49) : 9793 - 9799
  • [47] Influence of the sulfonyl group on the biological activity of 2-sulfonarylhydrazinylidene 1,3-dicarbonyl compounds
    Elkina, N. A.
    Khudina, O. G.
    Burgart, Ya. V.
    Shchegolkov, E. V.
    Serebryakova, O. G.
    Rudakova, E. V.
    Boltneva, N. P.
    Kovaleva, N. V.
    Makhaeva, G. F.
    Gerasimova, N. A.
    Evstigneeva, N. P.
    Saloutin, V. I.
    RUSSIAN CHEMICAL BULLETIN, 2024, 73 (06) : 1766 - 1774
  • [48] Copper-Catalyzed Condensation Reaction of Amines with 1,3-Dicarbonyl Compounds to Produce Enaminones
    Qu, Yiping
    Wang, Longxiang
    Zhou, Xiaoyu
    Feng, Xiujuan
    Bao, Ming
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2013, 33 (04) : 860 - 865
  • [49] Base-Catalyzed One-Pot Synthesis of Unsymmetrical Fluorenes from Aromatic ortho-Dialdehydes and 1,3-Dicarbonyl Compounds
    Seo, Ue Ryung
    Chung, Young Keun
    Lee, Chulbom
    CHEMCATCHEM, 2016, 8 (06) : 1051 - 1054
  • [50] Cu(II)-Catalyzed Synthesis of 2,3,6-Trisubstituted Pyridines from Saturated Ketone and Alkynones/1,3-Dicarbonyl Compounds
    Zhan, Zhen Z.
    He, Jian P.
    Jiang, Peng B.
    Zhang, Ming M.
    Wang, He S.
    Luo, Nan
    Huang, Guo S.
    CHEMISTRYSELECT, 2021, 6 (17): : 4160 - 4165