Photoinduced Synthesis of P-Perfluoroalkylated Phosphines from Triarylphosphines and Their Application in the Copper-Free Cross-Coupling of Acid Chlorides and Terminal Alkynes

被引：15

作者：

Kawaguchi, Shin-ichi ^{[1
]}

Minamida, Yoshiaki ^{[1
]}

Okuda, Takumi ^{[1
]}

Sato, Yuki ^{[1
]}

Saeki, Tomokazu ^{[1
]}

Yoshimura, Aya ^{[1
]}

Nomoto, Akihiro ^{[1
]}

Ogawa, Akiya ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, Sakai, Osaka 5998531, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 11期

关键词：

cleavage reactions; cross-coupling; fluorinated ligands; palladium; phosphanes; PALLADIUM-CATALYZED PHOSPHINATION; NUCLEAR-MAGNETIC-RESONANCE; SOLVENT-FREE SYNTHESIS; ACYL CHLORIDES; HETEROARYLPHOSPHORUS COMPOUNDS; ARYL IODIDES; CHEMISTRY; BROMIDES; LIGANDS; YNONES;

D O I：

10.1002/adsc.201500294

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A practical synthesis yielding P-perfluoroalkylated phosphines from triarylphosphines and perfluoroalkyl iodides has been developed. The photoinduced reaction involves the substitution of aryl groups on the phosphorus atom with perfluoroalkyl groups to successfully afford P-perfluoroalkylated phosphines. In addition, the P-perfluoroalkylated phosphines were found to promote the Cu-free cross-coupling reaction of acid chlorides with terminal alkynes.

引用

页码：2509 / 2519

页数：11

共 70 条

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