Synthesis and complexation of a new branched vic-dioxime

被引：17
|
作者：
Musluoglu, E
Bekaroglu, O
机构：
[1] TUBITAK,MARMARA RES CTR,BASIC SCI RES INST,DEPT CHEM,TR-41470 GEBZE,KOCAELI,TURKEY
[2] ISTANBUL TECH UNIV,DEPT CHEM,TR-80626 MASLAK,ISTANBUL,TURKEY
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 39卷 / 3-4期
关键词：
vic-dioxime; cobalt; nickel; copper; palladium; platinum; dendrimers;
D O I：
10.1080/00958979608024333
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new vic-dioxime; 1,2-Bis{[di-ten-butyl-4-amino-4-(2-(tert-butoxycarbonyl)ethyl)heptanedioate]-N-yl}glyoxime (H(2)L) has been prepared from di-tert-butyl-4-amino-4-[2-(tert-butoxycarbonyl)-ethyl]heptanedioate (I) and cyanogen-di-N-oxide Transition metal complexes with Ni(II), Pd(II), Cu(II), Co(II) and Pt(II) have been synthesized with a metal-ligand ratio of 1:2. All complexes are very soluble in common organic solvents. H-1 and C-13 NMR, IR, MS and electronic spectrum data are presented. Electrochemical properties of H(2)L and three complexes (Cu, Co and Pt) were investigated by cyclic voltammetry.
引用
收藏
页码：253 / 264
页数：12
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