Corn Stalks -Derived Carbon-SnO2 Composite as Anodes for Lithium-Ion Batteries

被引:7
作者
Zhang, Zhiqiang [1 ]
Xue, Jinshen [1 ]
Song, Kexian [1 ]
Wang, Xiaofeng [3 ]
Yu, Kaifeng [1 ]
Li, Xiangji [1 ,2 ]
机构
[1] Minist Educ, Key Lab Automobile Mat, Coll Mat Sci & Engn, Changchun, Jilin, Peoples R China
[2] Jilin Univ, Roll Forging Inst, Changchun 130022, Jilin, Peoples R China
[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China
来源
CHEMISTRYSELECT | 2019年 / 4卷 / 05期
基金
美国国家科学基金会;
关键词
Biomass; Corn stalks; Electrochemistry; Tin oxide; Three-dimensional structure; MESOPOROUS ACTIVATED CARBON; HIGH-PERFORMANCE ANODE; HIGH-STABILITY; SNO2; STORAGE;
D O I
10.1002/slct.201803384
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
SnO2 is known as a promising anode candidate for lithium-ion batteries (LIBs), but suffers from the low electrical conductivity and severe volume variation during cycling, which restraint its practical applications. To solve these issues, we successfully fabricated the three-dimensional structure of carbon obtained from corn stalks and SnO2 composites. The materials exhibit excellent electrochemical performance. After 100 cycles, it shows a reversible capacity of 691 mA h g(-1) at a current density of 0.2 C. Excellent cycle performance is due to the unique structure, which has a strong internal chemical bond between the SnO2 nanoparticles (SnO2 NPs) and the carbon skeleton, preventing SnO2 NPs from falling off the 3D network during the cycle. This work may provide a broader vision into synthesising C-SnO2 composites for high-performance anode materials of LIBs.
引用
收藏
页码:1557 / 1561
页数:5
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