Synthesis of 2-phosphoro-1,2-thiazetidine 1,1-dioxide

被引：0

作者：

Mielniczak, G ^{[1
]}

Lopusinski, A ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

HETEROATOM CHEMISTRY | 1999年 / 10卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of phosphorochloridites 5a-c with an equimolar amount of 1,2-thiazetidine 1,1-dioxide (2) or L(-)-3-carboethoxy-1,2-thiazetidine 1,1-dioxide (7) in the presence of triethylamine, affords the N-phosphitylated beta-sultams 6a-b and L(-)-8a,c. Their oxidation by addition of oxygen, sulfur, or selenium results in formation of stable organophosphorus beta-sultams 10a-b, L(-)-11a,c, 12a, 13a, L(-)-14c, and L( -)-15c. (C) 1999 John Wiley & Sons, Inc.

引用

页码：61 / 67

页数：7

共 25 条

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