Metal Nitrite: A Powerful Oxidizing Reagent

被引：41

作者：

Baidya, Mahiuddin ^{[1
]}

Yamamoto, Hisashi ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 35期

基金：

美国国家科学基金会;

关键词：

DIELS-ALDER REACTIONS; NITROXYL DELIVERY AGENTS; N-O HETERODIENOPHILES; ASYMMETRIC-SYNTHESIS; ORGANIC-SYNTHESIS; AMINO-ALCOHOLS; REDUCING AGENT; CYCLOADDITIONS; DERIVATIVES; AMINATION;

D O I：

10.1021/ja206736q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and simple source of nitroso reagents and their oxidation reactions are described. The combination of a Lewis acid and a metal nitrite was applied to the oxidation of silyl enol ethers. Amino acid and peptide derivatives were easily accessed through in situ C-C bond cleavage of fully substituted silyl enol ethers upon oxidation.

引用

收藏

页码：13880 / 13882

页数：3

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