Catalytic application of Mo-incorporated SBA-1 mesoporous molecular sieves to partial oxidation of methane

被引:36
作者
Dai, LX
Teng, YH
Tabata, K
Suzuki, E
Tatsumi, T
机构
[1] Res Inst Innovat Technol Earth, RITE, Kyoto 6190292, Japan
[2] Yokohama Natl Univ, Fac Engn, Div Mat Sci & Chem Engn, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
关键词
synthesis; mesoporous materials; Mo-SBA-1; methane; partial oxidation;
D O I
10.1016/S1387-1811(01)00236-0
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Mo-incorporated SBA-1 mesoporous molecular sieves have been synthesized under acidic conditions using cetyl-triethylammonium bromide as a surfactant and used as catalysts for partial oxidation of methane with oxygen as an oxidant. In the partial oxidation of methane the catalytic performance of Mo-SBA-1 materials directly synthesized from the Mo-containing gel were superior to those of Mo-impregnated pure siliceous SBA-1 and amorphous silica. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:573 / 580
页数:8
相关论文
共 19 条
  • [1] THE PARTIAL OXIDATION OF METHANE ON MOO3/SIO2 CATALYSTS - INFLUENCE OF THE MOLYBDENUM CONTENT AND TYPE OF OXIDANT
    BANARES, MA
    FIERRO, JLG
    MOFFAT, JB
    [J]. JOURNAL OF CATALYSIS, 1993, 142 (02) : 406 - 417
  • [2] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
    BECK, JS
    VARTULI, JC
    ROTH, WJ
    LEONOWICZ, ME
    KRESGE, CT
    SCHMITT, KD
    CHU, CTW
    OLSON, DH
    SHEPPARD, EW
    MCCULLEN, SB
    HIGGINS, JB
    SCHLENKER, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
  • [3] SELECTIVE OXIDATION OF METHANE TO METHANOL AT HIGH-PRESSURES
    CASEY, PS
    MCALLISTER, T
    FOGER, K
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (05) : 1120 - 1125
  • [4] Comparison of silica-supported MoO3 and V2O5 catalysts in the selective partial oxidation of methane
    Faraldos, M
    Banares, MA
    Anderson, JA
    Hu, HC
    Wachs, IE
    Fierro, JLG
    [J]. JOURNAL OF CATALYSIS, 1996, 160 (02) : 214 - 221
  • [5] Development of active oxide catalysts for the direct oxidation of methane to formaldehyde
    Herman, RG
    Sun, Q
    Shi, CL
    Klier, K
    Wang, CB
    Hu, HC
    Wachs, IE
    Bhasin, MM
    [J]. CATALYSIS TODAY, 1997, 37 (01) : 1 - 14
  • [6] HUE Q, 1995, SCIENCE, V268, P1324
  • [7] ORGANIZATION OF ORGANIC-MOLECULES WITH INORGANIC MOLECULAR-SPECIES INTO NANOCOMPOSITE BIPHASE ARRAYS
    HUO, QS
    MARGOLESE, DI
    CIESLA, U
    DEMUTH, DG
    FENG, PY
    GIER, TE
    SIEGER, P
    FIROUZI, A
    CHMELKA, BF
    SCHUTH, F
    STUCKY, GD
    [J]. CHEMISTRY OF MATERIALS, 1994, 6 (08) : 1176 - 1191
  • [8] Surfactant control of phases in the synthesis of mesoporous silica-based materials
    Huo, QS
    Margolese, DI
    Stucky, GD
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (05) : 1147 - 1160
  • [9] RAMAN AND ULTRAVIOLET SPECTROSCOPIC CHARACTERIZATION OF MOLYBDENA ON ALUMINA CATALYSTS
    JEZIOROWSKI, H
    KNOZINGER, H
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (09) : 1166 - 1173
  • [10] Synthesis and pore size control of cubic mesoporous silica SBA-1
    Kim, MJ
    Ryoo, R
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (02) : 487 - 491