Search for novel amorphous alloys with high crystallization temperature by combinatorial arc plasma deposition

被引：18

作者：

Hata, Seiichi ^{[1
]}

Sakurai, Junpei ^{[2
]}

Yamauchi, Ryusuke ^{[2
]}

Shimokohbe, Akira ^{[2
]}

机构：

[1] Tokyo Inst Technol, Frontier Collaborat Res Ctr, Midori Ku, Yokohama, Kanagawa 4259, Japan

[2] Tokyo Inst Technol, Precis & Intelligence Lab, Midori Ku, Yokohama, Kanagawa 4259, Japan

来源：

APPLIED SURFACE SCIENCE | 2007年 / 254卷 / 03期

关键词：

amorphous alloy; crystallization temperature; combinatorial search; combinatorial arc plasma deposition;

D O I：

10.1016/j.apsusc.2007.05.092

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper describes a combinatorial search for novel amorphous alloys with high crystallization temperatures (T(x)) using combinatorial arc plasma deposition (CAPD). The CAPD technique can deposit 1089 (33 x 33) thin film samples with different compositions on a substrate at one time. These 1089 samples on the substrate are individually referred to as CAPD samples and collectively referred to as a thin film library. Thin film libraries of Ir-Zr-Fe, Ir-Zr-Al, Mo-Zr-Al, Mo-Zr-Si, Ru-Zr-Fe and Ru-Zr-Si were deposited by CAPD. The compositions and phases of the CAPD samples were measured by energy dispersive X-ray fluorescence spectrometry and X-ray diffractometry, respectively. The results revealed that each library included amorphous CAPD samples. Since it is impossible to measure the T(x), fracture strength, fracture strain and Young's modulus of the CAPD samples by conventional measurement methods, larger samples having the same compositions as the amorphous CAPD samples were fabricated by a sputtering system. Since all CAPD samples of Ir-Zr-Fe and Ir-Zr-Al were too brittle, their corresponding sputter-deposited samples were not prepared. Sputter-deposited Mo-Zr-Al, Mo-Zr-Si, Ru-Zr-Fe and Ru-Zr-Si samples with similar to 50 at.% Mo- or Ru-content were fabricated, and T(x) and mechanical properties of these sputter-deposited samples were evaluated. All the sputter-deposited samples of Mo-Zr-Al and Mo-Zr-Si showed high T(x) exceeding 973 K and as well as brittle characteristics. Ru(50)Zr(35)Fe(10) samples showed high T(x) exceeding 1273 K and a low fracture strength of 0.26 GPa. Samples of Ru(51)Zr(5)Si(44) showed a high T(x) of 923 K and a high fracture strength of 1.25 GPa. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：738 / 742

页数：5

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