Oxidative Decarboxylation of Benzilic Acid by a Biomimetic Iron(II) Complex: Evidence for an Iron(IV)-Oxo-Hydroxo Oxidant from O2

被引：62

作者：

Paria, Sayantan ^{[3
]}

Que, Lawrence, Jr. ^{[1
,2
]}

Paine, Tapan Kanti ^{[3
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

[3] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 47期

基金：

美国国家科学基金会;

关键词：

benzilic acid; bioinorganic chemistry; cis-dihydroxylation; iron; oxidative decarboxylation; OLEFIN CIS-DIHYDROXYLATION; OXYGEN ACTIVATION; BENZOATE 1,2-DIOXYGENASE; PSEUDOMONAS-PUTIDA; NONHEME; DIOXYGENASE; BIOSYNTHESIS; CHEMISTRY; CATALYSTS; CLEAVAGE;

D O I：

10.1002/anie.201103971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

O 2-dependent transformation: An iron(II)-benzilate complex of a tridentate N3 donor ligand reacts with O 2 to undergo oxidative decarboxylation. Cyclohexene is selectively converted into cis-cyclohexane-1,2- diol in the reaction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11129 / 11132

页数：4

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