A Robust New Motif for Supramolecular Construction: The Edge to Edge Aryl CH•••N Dimer

被引：12

作者：

Bishop, Roger ^{[1
]}

Marjo, Christopher E. ^{[1
]}

Scudder, Marcia L. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 313卷

基金：

澳大利亚研究理事会;

关键词：

hydrogen bonding; CH center dot center dot center dot N interactions; inclusion compounds; host-guest compounds; polyhalocarbons; aromatic heterocycles;

D O I：

10.1080/10587259808044261

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The edge to edge aryl CH center dot center dot center dot N dimer is a previously unrecognised intermolecular hydrogen bonded lattice packing motif; a search of the Cambridge Structural Database revealing that it is widespread amongst many classes of aromatic nitrogen-containing solids. This weak attractive interaction can be retained throughout crystal engineering studies as typified by the systematic modification of the diquinoline 1 into host-guest compounds formed by its dibromo derivative 2. The latter is a molecule designed to form multimolecular inclusion compounds specifically with small polyhalocarbon guests.

引用

页码：75 / 83

页数：9

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