Removal of mercury from coal by mild pyrolysis and leaching behavior of mercury

被引：68

作者：

Iwashita, A ^{[1
]}

Tanamachi, S ^{[1
]}

Nakajima, T ^{[1
]}

Takanashi, H ^{[1
]}

Ohki, A ^{[1
]}

机构：

[1] Kagoshima Univ, Fac Engn, Dept Bioengn, Kagoshima 8900065, Japan

来源：

FUEL | 2004年 / 83卷 / 06期

关键词：

mercury in coal; removal by mild pyrolysis; leaching;

D O I：

10.1016/j.fuel.2003.05.004

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Various types of coals were subjected to the pyrolysis at 300 and 400 degreesC (mild pyrolysis), and the removal of Hg from coal was determined. The removal efficiency of Hg greatly varied with coal type from 20 to 80%. The removal efficiency was dependent neither on the specific surface area of coal nor on the particle size of coal. The leaching of Hg from coal was tested using sulfur-containing chelating agents such as 3-mercaptopropionic acid (MPA). The Hg leaching efficiency also varied greatly with coal type. There was a good correlation between the degree of %Hg leaching in the MPA leaching and that of %Hg removal in the mild pyrolysis. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：631 / 638

页数：8

共 28 条

[1]

[Anonymous], 1992, IEACR49

[2]

BLAND AE, 2001, P 26 INT TECHN C COA, P457

[3]

DAVIDSON RM, 2000, CCC36 IEA COAL RES, P1

[4]

DAVIDSON RM, 1996, IEAPER21 IEA COAL RE, P17

[5]

Demir I., 2001, FUEL CHEM DIV, V46, P289

[6] Modes of occurrence of mercury in coals from Guizhou, People's Republic of China [J].

Feng, X ;

Hong, Y .

FUEL, 1999, 78 (10) :1181-1188

[7] CHELATING PROPERTIES OF BETA-MERCAPTOPROPIONIC ACID [J].

FERNANDO, Q ;

FREISER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) :4928-4931

[8]

Finkelman R.B., 1995, ENV ASPECTS TRACE EL

[9] COMBUSTION AND LEACHING BEHAVIOR OF ELEMENTS IN THE ARGONNE PREMIUM COAL SAMPLES [J].

FINKELMAN, RB ;

PALMER, CA ;

KRASNOW, MR ;

ARUSCAVAGE, PJ ;

SELLERS, GA ;

DULONG, FT .

ENERGY & FUELS, 1990, 4 (06) :755-766

[10] Use of a chelating agent to determine the metal availability for leaching from soils and wastes [J].

Garrabrants, AC ;

Kosson, DS .

WASTE MANAGEMENT, 2000, 20 (2-3) :155-165

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