Synthesis of the tricyclic core structure of vindoline

被引：24

作者：

Guo, ZH ^{[1
]}

Schultz, AG ^{[1
]}

机构：

[1] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 05期

关键词：

vindoline; synthesis; 1,3-dipolar cycloaddition; birch reduction-alkylation;

D O I：

10.1016/j.tetlet.2003.11.115

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthesis of the core tricyclic structure (18) of vindoline has been achieved using the strategy, which features an intramolecular 1,3-dipolar cycloaddition of the azido dienone (12) to give aziridine (13) with complete region- and stereocontrol. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：919 / 921

页数：3

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