A More Reactive Trigonal-Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site

被引：102

作者：

England, Jason ^{[2
,3
]}

Guo, Yisong ^{[1
]}

Van Heuvelen, Katherine M. ^{[2
,3
]}

Cranswick, Matthew A. ^{[2
,3
]}

Rohde, Gregory T. ^{[2
,3
]}

Bominaar, Emile L. ^{[1
]}

Muenck, Eckard ^{[1
]}

Que, Lawrence, Jr. ^{[2
,3
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[3] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 31期

基金：

美国国家科学基金会;

关键词：

TAURINE/ALPHA-KETOGLUTARATE DIOXYGENASE; SPECTROSCOPIC EVIDENCE; ALIPHATIC HALOGENASE; ALKANE HYDROXYLATION; FE(IV) INTERMEDIATE; OXYGEN ACTIVATION; ESCHERICHIA-COLI; FE-IV=O; NONHEME; OXO;

D O I：

10.1021/ja2040909

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trigonal-bipyramidal high-spin (S = 2) oxoiron(IV) complex [Fe-IV(O)(TMG(2)dien)(CH3CN)](2+) (7) was synthesized and spectroscopically characterized. Substitution of the CH3CN ligand by anions, demonstrated here for X = N-3(-) and Cl-, yielded additional S = 2 oxoiron(IV) complexes of general formulation [Fe-IV(O)(TMG(2)dien)(X)](+) (7-X). The reduced steric bulk of 7 relative to the published S = 2 complex [FeIV(O)(TMG(3)tren)](2+) (2) was reflected by enhanced rates of intermolecular substrate oxidation.

引用

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页码：11880 / 11883

页数：4

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