Electronic absorption spectra of trimethylacetatocobalt(II) 2,2′-dipyridyl complexes

被引:0
|
作者
Golovaneva, IF [1 ]
Mikhailova, TB [1 ]
Fomina, IG [1 ]
Sidorov, AA [1 ]
Eremenko, IL [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
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D O I
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Electronic absorption spectra (in solution and in solid) of 2,2'-dipyridyl trimethylacetato cobalt(II) complexes were measured in the UV and visible ranges (50 000-11 100 cm(-1)): [Co(Dipy)(2)(OOCCMe3)(2)] (1), [Co(Dipy)(OOCCMe3)(eta (2)-OOCCMe3)(PhNH2)](2), and [Co-2(DiPY)(OOCCMe3)2(mu -OOCCMe3)(2)(mu -O2H)] (3). The spectroscopic data were analyzed, and assignment of electronic transitions observed in the spectra was done.
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页码:1409 / 1412
页数:4
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