catena-Poly[[bis(4-methoxybenzoato)-copper(II)]-μ-1,1′-(oxydiethylene)-diimidazole-κ2N3:N3′]

被引：0

作者：

Wei, Guo-Hua ^{[1
]}

Zhang, Lai-Ping ^{[1
]}

Ma, Ji-Cheng ^{[1
]}

Yang, Jin ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807053007

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C7H4O3)(2)(C10H14N4O)](n), the Cu-II atom lies on a centre of symmetry and is four-coordinated by two N atoms from two 1,1 '-(oxydiethylene)diimidazole (BIE) ligands and two O atoms from two 4-methoxybenzoate anions in a square-planar geometry. Each BIE ligand links two Cu-II atoms to form an infinite chain structure along the c axis. The 4-methoxybenzoate anion, as a terminal ligand, attaches to both sides of the BIE-Cu-II chains.

引用

页码：M2866 / U2184

页数：11

共 8 条

[1] Syntheses and characterizations of copper(II) polymeric complexes constructed from 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Shi, Q ;

Sun, DF ;

Hong, MC ;

Bi, WH ;

Zhao, YJ .

INORGANIC CHEMISTRY, 2002, 41 (23) :6161-6168

[2]

Higashi T., 1995, ABSCOR

[3] Networks with hexagonal circuits in co-ordination polymers of metal ions (ZnII, CdII) with 1,1′-(1,4-butanediyl)bis(imidazole) [J].

Ma, JF ;

Liu, JF ;

Xing, Y ;

Jia, HQ ;

Lin, YH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (14) :2403-2407

[4]

Rigaku, 1998, PROCESS AUTO

[5]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR, P38

[6]

SHELDRICK GM, 1990, SHELXTL PLUS

[7] Two new CuII coordination polymers:: Studies of topological networks and water clusters [J].

Yang, J ;

Ma, MF ;

Liu, YY ;

Ma, JC ;

Jia, HQ ;

Hu, NH .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (06) :1208-1215

[8] Hydrothermal syntheses, crystal structures, and properties of a novel class of 3,3′,4,4′-benzophenone-tetracarboxylate (BPTC) polymers [J].

Zhang, J ;

Li, ZJ ;

Kang, Y ;

Cheng, JK ;

Yao, YG .

INORGANIC CHEMISTRY, 2004, 43 (25) :8085-8091

← 1 →