Catalytic transformations of the major terpene feedstocks

被引:182
作者
Swift, KAD [1 ]
机构
[1] Quest Int, Ashford TN24 0LT, Kent, England
关键词
catalysis; terpene; hydrogenation; hydrogenolysis; dehydrogenation; rearrangement; isomerization; aromatization; epoxidation; turpentine; monoterpene; pinene; limonene; carene; geraniol; citronellol; citral; citronellal;
D O I
10.1023/B:TOCA.0000013549.60930.da
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A review covering some of the key catalytic transformations of the major monoterpene feedstocks. Monoterpenes are key ingredients in the flavor and fragrance industry, with alpha- and beta-pinene (obtained from turpentine) being some of the most important. The review focuses on the hydrocarbons; pinene, limonene, carene, and the interconversion of the monooxygenates; geraniol/nerol, citronellol, citral, and citronellal. The major areas covered are catalytic hydrogenation/hydrogenolysis, dehydrogenation, rearrangement/isomerization/aromatization, reactions with carbon monoxide, epoxidation, and the addition of alcohols and acids.
引用
收藏
页码:143 / 155
页数:13
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