Controlled-release urea encapsulated by ethyl cellulose/butyl acrylate/vinyl acetate hybrid latex

被引:10
作者
Li, Yue [1 ]
Zhen, Da [2 ]
Liao, Shuijiao [1 ]
Zhu, Duanwei [3 ]
Yang, Xun [1 ]
机构
[1] Huazhong Agr Univ, Coll Basic Sci, Wuhan 430070, Hubei, Peoples R China
[2] Hubei Univ Technol, Coll Bioengn, Wuhan 430068, Hubei, Peoples R China
[3] Huazhong Agr Univ, Lab Plant Nutr & Ecol Environm Res, Ctr Microelement Res, Wuhan 430070, Hubei, Peoples R China
基金
国家重点研发计划;
关键词
coated urea; ethyl cellulose/butyl acrylate/vinyl acetate; hybrid latex; emulsion polymerization; controlled-release ability; GRAFTING COPOLYMER; STARCH; ETHYLCELLULOSE; FERTILIZERS;
D O I
10.2478/pjct-2018-0062
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Fertilizer encapsulation through polymer membranes can reduce fertilizer losses and minimize environmental pollution. In this paper, an emulsion of ethyl cellulose (EC)/vinyl acetate (VAc)/butyl acrylate (BA) was successfully prepared by pre-emulsified semi-continuous seed emulsion polymerization. EC/BA/VAc films showed biodegradability. The influence of the EC content on the properties of EC/BA/VAc films was also investigated by DSC, a water absorbency analysis, etc. Controlled-release urea encapsulated by EC/BA/VAc latex was prepared in a film coating machine and conformed to the standards for slow-release fertilizers of the Committee of European Normalization. The release of urea from controlled-release urea encapsulated by EC/BA/VAc latex containing 0%, 5%, 10%, and 15% EC was 75.1%, 65.8%, 70.1% and 84.1%, respectively, after 42 days, and controlled-release urea encapsulated by EC/BA/VAc latex (5% EC) had the best controlled-release ability. Therefore, controlled-release urea encapsulated by EC/BA/VAc latex has many potential applications in agricultural industry.
引用
收藏
页码:108 / 112
页数:5
相关论文
共 31 条
[2]   Controlled release of urea encapsulated by starch-g-poly(L-lactide) [J].
Chen, Li ;
Xie, Zhigang ;
Zhuang, Xiuli ;
Chen, Xuesi ;
Jing, Xiabin .
CARBOHYDRATE POLYMERS, 2008, 72 (02) :342-348
[3]   New Ethyl Cellulose/Acrylic Hybrid Latexes and Coatings via Miniemulsion Polymerization [J].
Chen, R. ;
Chu, F. ;
Gauthier, C. ;
Chazeau, L. ;
Chaduc, I. ;
Bourgeat-Lami, E. ;
Lansalot, M. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (11) :2329-2339
[4]   Role of Polymeric Coating on the Phosphate Availability as a Fertilizer: Insight from Phosphate Release by Castor Polyurethane Coatings [J].
da Cruz, Diego Fernandes ;
Bortoletto-Santos, Ricardo ;
Fernandes Guimaraes, Gelton Geraldo ;
Polito, Wagner Luiz ;
Ribeiro, Caue .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2017, 65 (29) :5890-5895
[5]   Characterization of polymeric dispersions of dimenhydrinate in ethyl cellulose for controlled release [J].
Desai, J ;
Alexander, K ;
Riga, A .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2006, 308 (1-2) :115-123
[6]   Controlled release fertilizers using superabsorbent hydrogel prepared by gamma radiation [J].
Elbarbary, Ahmed M. ;
Ghobashy, Mohamed Mohamady .
RADIOCHIMICA ACTA, 2017, 105 (10) :865-876
[7]   STUDIES ON SLOW-RELEASE FERTILIZERS .2. A METHOD FOR EVALUATION OF NUTRIENT RELEASE RATE FROM SLOW-RELEASING FERTILIZERS [J].
GAMBASH, S ;
KOCHBA, M ;
AVNIMELECH, Y .
SOIL SCIENCE, 1990, 150 (01) :446-450
[8]  
General Administration of Quality Supervision Inspection and Quarantine of China (AQSIQ), 2006, PLASTICS DETERMINATI
[9]   Controlled-release fertilizer encapsulated by starch/polyvinyl alcohol coating [J].
Han, Xiaozhao ;
Chen, Sensen ;
Hu, Xianguo .
DESALINATION, 2009, 240 (1-3) :21-26
[10]  
Hong K, 2000, J APPL POLYM SCI, V78, P894, DOI 10.1002/1097-4628(20001024)78:4<894::AID-APP240>3.0.CO