Post-annealing treatment of a-GeSe thin films for photovoltaic application

被引:30
作者
Zi, Wei [1 ]
Mu, Fangling [1 ]
Lu, Xiaoman [1 ]
Cao, Yang [1 ]
Xie, Yanping [2 ]
Fang, Liang [1 ]
Cheng, Nian [1 ]
Zhao, Zhiqiang [1 ]
Xiao, Zhenyu [1 ]
机构
[1] Xinyang Normal Univ, Energy Saving Bldg Mat Innovat Collaborat Ctr Hen, Xinyang 464000, Henan, Peoples R China
[2] Xinyang Normal Univ, Anal & Testing Ctr, Xinyang 464000, Henan, Peoples R China
关键词
GeSe; Thin-film solar cells; Post-annealing treatment; Vacuum evaporation; SOLAR-CELLS; P-LAYER; EFFICIENCY; NANOSHEETS;
D O I
10.1016/j.solener.2020.02.086
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
p-GeSe is a promising absorber material for thin-film solar cell. In this letter, p-GeSe thin films were fabricated by post-annealing treatment of a-GeSe films. We systematically studied the effects of annealing time on the crystallinity, surface morphology and photoelectric properties of GeSe films, and we found the bandgaps, optical constant and conductivity of GeSe films have shown significant variations when GeSe films transformed from amorphous to polycrystalline. The bandgap of GeSe film can be tuned in a range of 1.17-1.42 eV and the hole mobility can reach as high as 15.02 cm(2) V(-1)s(-1). Finally, a thin-film solar cell based on FTO/CdS/p-GeSe/Au configuration was fabricated and has realized an efficiency of 0.65% and a short circuit current of 12.61 mA/cm(2).
引用
收藏
页码:837 / 843
页数:7
相关论文
共 32 条
  • [1] [Anonymous], 2019, 46 IEEE PVSC CHIC IL
  • [2] Tin and germanium monochalcogenide IV-VI semiconductor nanocrystals for use in solar cells
    Antunez, Priscilla D.
    Buckley, Jannise J.
    Brutchey, Richard L.
    [J]. NANOSCALE, 2011, 3 (06) : 2399 - 2411
  • [3] RAMAN-SCATTERING AND INFRARED REFLECTIVITY IN GESE
    CHANDRASEKHAR, HR
    ZWICK, U
    [J]. SOLID STATE COMMUNICATIONS, 1976, 18 (11-1) : 1509 - 1513
  • [4] Highly oriented GeSe thin film: self-assembly growth via the sandwiching post-annealing treatment and its solar cell performance
    Chen, Binwen
    Ruan, Yurong
    Li, Jianmin
    Wang, Weihuang
    Liu, Xinlian
    Cai, Huiling
    Yao, Liquan
    Zhang, Jian-Min
    Chen, Shuiyuan
    Chen, Guilin
    [J]. NANOSCALE, 2019, 11 (09) : 3968 - 3978
  • [5] Magnetron sputtering deposition of GeSe thin films for solar cells
    Chen, Binwen
    Chen, Guilin
    Wang, Weihuang
    Cai, Huiling
    Yao, Liquan
    Chen, Shuiyuan
    Huang, Zhigao
    [J]. SOLAR ENERGY, 2018, 176 : 98 - 103
  • [6] Optimization of CBD CdS process in high-efficiency Cu(In,Ga)Se2-based solar cells
    Contreras, MA
    Romero, MJ
    Hasoon, BTE
    Noufi, R
    Ward, S
    Ramanathan, K
    [J]. THIN SOLID FILMS, 2002, 403 : 204 - 211
  • [7] Hydrogenated nanocrystalline silicon p-layer in amorphous silicon n-i-p solar cells
    Du, WH
    Liao, XB
    Yang, XS
    Povolny, H
    Xiang, XB
    Deng, XM
    Sun, K
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (7-8) : 1098 - 1104
  • [8] Physical properties of vanadium pentoxide sol gel films
    El Mandouh, ZS
    Selim, MS
    [J]. THIN SOLID FILMS, 2000, 371 (1-2) : 259 - 263
  • [9] Green MA, 2020, PROG PHOTOVOLTAICS, V28, P3, DOI [10.1002/pip.3228, 10.1002/pip.3171]
  • [10] SUBLIMATION KINETICS OF GESE SINGLE-CRYSTALS
    IRENE, EA
    WIEDEMEIER, H
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 411 (02): : 182 - 192