Evidence for electric field-assisted back-electron transfer through a methylene bond in a linked compound of phenanthrene and phthalimide in a polymer film

被引：17
作者：
Kawabata, H
Ohta, N [1 ]
Arakawa, H
Ashida, M
Kohtani, S
Nakagaki, R
机构：
[1] Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 0600810, Japan
[2] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan
[3] Kanazawa Univ, Fac Pharmaceut Sci, Kanazawa, Ishikawa 9200934, Japan
来源：
JOURNAL OF CHEMICAL PHYSICS | 2001年 / 114卷 / 18期
关键词：
D O I：
10.1063/1.1370566
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Fluorescence emitted from phenanthrene linked to phthalimide by a short methylene chain is unusually enhanced by an electric field in a polymer film. Back-electron transfer which produces the fluorescent state of phenanthrene occurs through a short methylene bond following photoinduced electron transfer from phenanthrene to phthalimide, and its efficiency is enhanced by an electric field. (C) 2001 American Institute of Physics.
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页码：7723 / 7726
页数：4
相关论文
共 19 条
  • [1] ARAKAWA H, 1999, THESIS KANAZAWA U
  • [2] Boxer S. G., 1993, The Photosynthetic Reaction Center, P179
  • [3] Magnetic field effects on intramolecular exciplex fluorescence of chain-linked phenanthrene and N,N-dimethylaniline: Influence of chain length, solvent, and temperature
    Cao, H
    Fujiwara, Y
    Haino, T
    Fukazawa, Y
    Tung, CH
    Tanimoto, Y
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (10) : 2801 - 2813
  • [4] DESCHRYVER FC, 1977, ADV PHOTOCHEM, V10, P359
  • [5] ELECTROMODULATION OF FLUORESCENCE IN A CRYSTALLINE ORGANIC PHOTOCONDUCTOR (THIONAPHTHENINDOLE)
    KALINOWSKI, J
    STAMPOR, W
    DIMARCO, PG
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (06) : 4136 - 4148
  • [6] Liptay W., 1974, Excited states. Vol.1, P129
  • [7] PHOTOCHEMICAL CHARGE-TRANSFER PHENOMENA - PICOSECOND LASER PHOTOLYSIS STUDIES
    MATAGA, N
    [J]. PURE AND APPLIED CHEMISTRY, 1984, 56 (09) : 1255 - 1268
  • [8] External electric field effects on fluorescence of methylene-linked D-A systems in polymer films: (Carbazole)-(CH2)(n)-(terephthalic acid methyl ester)
    Ohta, N
    Koizumi, M
    Nishimura, Y
    Yamazaki, I
    Tanimoto, Y
    Hatano, Y
    Yamamoto, M
    Kono, H
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (50) : 19295 - 19302
  • [9] Electric-field-induced quenching of exciplex fluorescence and photocurrent generation in a mixture of ethylcarbazole and dimethyl terephthalate doped in a PMMA polymer film
    Ohta, N
    Umeuchi, S
    Nishimura, Y
    Yamazaki, I
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (19): : 3784 - 3790
  • [10] External electric field effects on fluorescence in an electron donor and acceptor system: Ethylcarbazole and dimethyl terephthalate in PMMA polymer films
    Ohta, N
    Koizumi, M
    Umeuchi, S
    Nishimura, Y
    Yamazaki, I
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (41) : 16466 - 16471
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