Bis[4′-(4-methylphenyl)-2,2′:6′,2"-terpyridine-κ3N,N′,N"]manganese(II)bis(perchlorate)

被引：6

作者：

Liu, Han-Guo ^{[1
]}

Qiu, Yong-Cai ^{[1
]}

Wu, Jian-Zhong ^{[1
]}

机构：

[1] S China Normal Univ, Dept Chem, Guangzhou 510631, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807040391

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Mn(C22H17N3)(2)](ClO4)(2), the MnN6 coordination geometry is distorted octahedral, involving the six N atoms of two 4'-(4-methylphenyl)- 2,2': 6',2 ''- terpyridine ( ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 ( 5) degrees. The packing involves intermolecular C - H center dot center dot center dot O hydrogen bonds between the ttp ligands and perchlorate anions. The latter are disordered over two positions, one with almost equal occupancy and the other in a ratio of ca 0.7: 0.3.

引用

页码：M2393 / U1335

页数：14

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